RESUMO
Zinc antimonides, particularly the ß-Zn4Sb3 compound, act as prototypes in the early phases of thermoelectric generator (TEG) development. However, their potential applications are constrained by structural instability at elevated temperatures. In this study, introducing a low concentration of aluminum (Al) achieves a highly stable Al-Zn4Sb3, exhibiting an improved peak zT value compared to undoped Zn4Sb3. Notably, a single-leg device utilizing a fully dense Al0.01Zn3.99Sb3 demonstrates an impressive conversion efficiency (η) of 3% even at a temperature difference (ΔT) of 225 K. This result represents an approximately 200% increase compared with the pristine one. The combination of dilute cationic doping and phase diagram engineering solidifies the potential of Zn4Sb3 as an efficient and sustainable green energy device.