Episodic fluid venting from sedimentary basins fueled by pressurized mudstones.

Subsurface sandstone reservoirs sealed by overlying, low-permeability layers provide capacity for long-term sequestration of anthropogenic waste. Leakage can occur if reservoir pressures rise sufficiently to fracture the seal. Such pressures can be generated within the reservoir by vigorous injection of waste or, over thousands of years, by natural processes. In either case, the precise role of intercalated mudstones in the long-term evolution of reservoir pressure remains unclear; these layers have variously been viewed as seals, as pressure sinks, or as pressure sources. Here, we use the geological record of episodic fluid venting in the Levant Basin to provide striking evidence for the pressure-source hypothesis. We use a Bayesian framework to combine recently published venting data, which record critical subsurface pressures since ∼2 Ma, with a stochastic model of pressure evolution to infer a pressure-recharge rate of ∼30 MPa/Myr. To explain this large rate, we quantify and compare a range of candidate mechanisms. We find that poroelastic pressure diffusion from mudstones provides the most plausible explanation for these observations, amplifying the ∼3 MPa/Myr recharge caused primarily by tectonic compression. Since pressurized mudstones are ubiquitous in sedimentary basins, pressure diffusion from mudstones is likely to promote seal failure globally.

Dynamics of Compression-Driven Gas-Liquid Displacement in a Capillary Tube.

We study two-phase displacement via the steady compression of an air reservoir connected to an oil-filled capillary tube. Our experiments and modeling reveal complex displacement dynamics depending on compression rate and reservoir volume that, for large reservoirs, depend on a single dimensionless compressibility number. We identify two distinct displacement regimes, separated by a critical value of the compressibility number. While the subcritical regime exhibits quasisteady displacement after an initial transient, the supercritical regime exhibits burstlike expulsion.

Gas Compression Systematically Delays the Onset of Viscous Fingering.

Using gas to drive liquid from a Hele-Shaw cell leads to classical viscous fingering. Strategies for suppressing fingering have received substantial attention. For steady injection of an incompressible gas, the intensity of fingering is controlled by the capillary number Ca. Here, we show that gas compression leads to an unsteady injection rate controlled primarily by a dimensionless compressibility number C. Increasing C systematically delays the onset of fingering at high Ca, highlighting compressibility as an overlooked but fundamental aspect of gas-driven fingering.

Evidence for massive emission of methane from a deep-water gas field during the Pliocene.

Geologic hydrocarbon seepage is considered to be the dominant natural source of atmospheric methane in terrestrial and shallow-water areas; in deep-water areas, in contrast, hydrocarbon seepage is expected to have no atmospheric impact because the gas is typically consumed throughout the water column. Here, we present evidence for a sudden expulsion of a reservoir-size quantity of methane from a deep-water seep during the Pliocene, resulting from natural reservoir overpressure. Combining three-dimensional seismic data, borehole data and fluid-flow modeling, we estimate that 18-27 of the 23-31 Tg of methane released at the seafloor could have reached the atmosphere over 39-241 days. This emission is ∼10% and ∼28% of present-day, annual natural and petroleum-industry methane emissions, respectively. While no such ultraseepage events have been documented in modern times and their frequency is unknown, seismic data suggest they were not rare in the past and may potentially occur at present in critically pressurized reservoirs. This neglected phenomenon can influence decadal changes in atmospheric methane.

Comprehensive comparison of pore-scale models for multiphase flow in porous media.

Multiphase flows in porous media are important in many natural and industrial processes. Pore-scale models for multiphase flows have seen rapid development in recent years and are becoming increasingly useful as predictive tools in both academic and industrial applications. However, quantitative comparisons between different pore-scale models, and between these models and experimental data, are lacking. Here, we perform an objective comparison of a variety of state-of-the-art pore-scale models, including lattice Boltzmann, stochastic rotation dynamics, volume-of-fluid, level-set, phase-field, and pore-network models. As the basis for this comparison, we use a dataset from recent microfluidic experiments with precisely controlled pore geometry and wettability conditions, which offers an unprecedented benchmarking opportunity. We compare the results of the 14 participating teams both qualitatively and quantitatively using several standard metrics, such as fractal dimension, finger width, and displacement efficiency. We find that no single method excels across all conditions and that thin films and corner flow present substantial modeling and computational challenges.

Wettability control on multiphase flow in patterned microfluidics.

Multiphase flow in porous media is important in many natural and industrial processes, including geologic CO2 sequestration, enhanced oil recovery, and water infiltration into soil. Although it is well known that the wetting properties of porous media can vary drastically depending on the type of media and pore fluids, the effect of wettability on multiphase flow continues to challenge our microscopic and macroscopic descriptions. Here, we study the impact of wettability on viscously unfavorable fluid-fluid displacement in disordered media by means of high-resolution imaging in microfluidic flow cells patterned with vertical posts. By systematically varying the wettability of the flow cell over a wide range of contact angles, we find that increasing the substrate's affinity to the invading fluid results in more efficient displacement of the defending fluid up to a critical wetting transition, beyond which the trend is reversed. We identify the pore-scale mechanisms-cooperative pore filling (increasing displacement efficiency) and corner flow (decreasing displacement efficiency)-responsible for this macroscale behavior, and show that they rely on the inherent 3D nature of interfacial flows, even in quasi-2D media. Our results demonstrate the powerful control of wettability on multiphase flow in porous media, and show that the markedly different invasion protocols that emerge-from pore filling to postbridging-are determined by physical mechanisms that are missing from current pore-scale and continuum-scale descriptions.

Lifetime of carbon capture and storage as a climate-change mitigation technology.

In carbon capture and storage (CCS), CO(2) is captured at power plants and then injected underground into reservoirs like deep saline aquifers for long-term storage. While CCS may be critical for the continued use of fossil fuels in a carbon-constrained world, the deployment of CCS has been hindered by uncertainty in geologic storage capacities and sustainable injection rates, which has contributed to the absence of concerted government policy. Here, we clarify the potential of CCS to mitigate emissions in the United States by developing a storage-capacity supply curve that, unlike current large-scale capacity estimates, is derived from the fluid mechanics of CO(2) injection and trapping and incorporates injection-rate constraints. We show that storage supply is a dynamic quantity that grows with the duration of CCS, and we interpret the lifetime of CCS as the time for which the storage supply curve exceeds the storage demand curve from CO(2) production. We show that in the United States, if CO(2) production from power generation continues to rise at recent rates, then CCS can store enough CO(2) to stabilize emissions at current levels for at least 100 y. This result suggests that the large-scale implementation of CCS is a geologically viable climate-change mitigation option in the United States over the next century.

Traction force microscopy in physics and biology.

Adherent cells, crawling slugs, peeling paint, sessile liquid drops, bearings and many other living and non-living systems apply forces to solid substrates. Traction force microscopy (TFM) provides spatially-resolved measurements of interfacial forces through the quantification and analysis of the deformation of an elastic substrate. Although originally developed for adherent cells, TFM has no inherent size or force scale, and can be applied to a much broader range of mechanical systems across physics and biology. In this paper, we showcase the wide range of applicability of TFM, describe the theory, and provide experimental details and code so that experimentalists can rapidly adopt this powerful technique.

Frictional fluid instabilities shaped by viscous forces.

Multiphase flows involving granular materials are complex and prone to pattern formation caused by competing mechanical and hydrodynamic interactions. Here we study the interplay between granular bulldozing and the stabilising effect of viscous pressure gradients in the invading fluid. Injection of aqueous solutions into layers of dry, hydrophobic grains represent a viscously stable scenario where we observe a transition from growth of a single frictional finger to simultaneous growth of multiple fingers as viscous forces are increased. The pattern is made more compact by the internal viscous pressure gradient, ultimately resulting in a fully stabilised front of frictional fingers advancing as a radial spoke pattern.

Interface pinning of immiscible gravity-exchange flows in porous media.

We study the gravity-exchange flow of two immiscible fluids in a porous medium and show that, in contrast with the miscible case, a portion of the initial interface remains pinned at all times. We elucidate, by means of micromodel experiments, the pore-level mechanism responsible for capillary pinning at the macroscale. We propose a sharp-interface gravity-current model that incorporates capillarity and quantitatively explains the experimental observations, including the x~t(1/2) spreading behavior at intermediate times and the fact that capillarity stops a finite-release current. Our theory and experiments suggest that capillary pinning is potentially an important, yet unexplored, trapping mechanism during CO(2) sequestration in deep saline aquifers.