1.
J Org Chem
; 78(15): 7482-7, 2013 Aug 02.
Artigo
em Inglês
| MEDLINE
| ID: mdl-23808633
RESUMO
An efficient and selective electrosynthesis of phenols and anilines from arylboronic acids in aqueous ammonia is achieved in an undivided cell. By simply changing the concentration of aqueous ammonia and the anode potential, good yields of phenols and anilines can be obtained chemoselectively with high reaction rates. We propose that anodic oxidation could have played an important role in these transformations.