RESUMO
Ozone advanced oxidation has been widely used in water treatment, but little research has been reported on the application of ozone to difficult-to-degrade mineral wastewater. In this paper, the effect of ozonation application in the treatment of copper mineral processing wastewater, which is difficult to be effectively treated by traditional processes due to its complex composition, was investigated. The effects of ozonation time, ozone concentration, temperature and pH on the degradation of organic compounds in the wastewater by ozonation were researched. It was found that the chemical oxygen demand (COD) of the wastewater could be reduced by 83.02% by ozonation under optimal treatment conditions. In addition, the mechanism of ozone degradation of the difficult-to-degrade wastewater was studied, and the reasons for the fluctuating variations of COD and ammonia nitrogen during ozonation treatment were explained.
Assuntos
Ozônio , Poluentes Químicos da Água , Purificação da Água , Águas Residuárias , Cobre , Poluentes Químicos da Água/química , Minerais , Ozônio/químicaRESUMO
The effect of static magnetic field-assisted freezing (MF) at different temperatures (-35, -30, -25, and -20 °C) on the muscle quality of pacific white shrimp (Litopenaeus vannamei) was evaluated to investigate the possibility of energy saving by MF. The results showed that the -35 °C MF treatment increased the water-holding capacity of shrimp muscle, and maintained the wholeness of the microstructure compared to -35 °C immersion freezing (control group, IF). With the increase in freezing temperature in the MF treatments, the size of ice crystals gradually increased, and the sensory properties of shrimp decreased. The water-holding capacity, sensory properties, and water distribution of shrimp muscle subjected to MF at -25 °C were still no significantly different from those of the IF at -35 °C (P > 0.05). In summary, the utilization of MF enhanced the quality of frozen pacific white shrimp, which has the potential to provide energy saving benefits.
Assuntos
Penaeidae , Água , Animais , Congelamento , Temperatura , Músculos , Alimentos Marinhos/análise , Penaeidae/químicaRESUMO
The effects of magnetic field-assisted immersion freezing (MF) with different intensities (20, 40, 60, and 80 mT) on the freezing process and muscle quality of white shrimp (Litopenaeus vannamei) were studied in the present study. The results showed that, compared with immersion freezing (IF), 60 mT MF (MF-60) shortened the total freezing time, reduced thawing loss and cooking loss, and helped to maintain the water holding capacity and texture properties of frozen shrimp samples. In addition, the increase in the L* value of frozen shrimp samples was also inhibited by MF-60. The result of water distribution revealed that MF-60 reduced the mobility and loss of immobilized water and free water. The microstructure of MF-60 was characterized by smaller pores, indicating that MF-60 promoted the generation of fine ice crystals. Overall, MF-60 was beneficial in reducing ice crystal size and inhibiting the loss of shrimp muscle quality loss during the freezing process.
RESUMO
Biochars were prepared by pyrolyzing mango peel waste at 300, 400, 500, 600 and 700 °C. Various characterizations were carried out to explore the effect of pyrolysis temperature on the biochars. The data indicated that the physical and chemical properties of biochar such as pH, element ratio, specific surface area and functional groups changed with the increase of pyrolysis temperature. The yield and contents of hydrogen, nitrogen and oxygen decreased, while contents of the ash and carbon, pH and specific surface area of the biochars increased. In addition, the molar ratios of H/C, O/C and (O + N)/C decreased. In this study, batch adsorption experiments for Cd(ii) adsorption were performed with initial Cd(ii) concentrations of 10-300 mg L-1, contact times of 0-2880 min, various pH (2-8) and biochar dose (1-20 g L-1). Langmuir isotherm and pseudo-second-order kinetics models were better fits than other models, suggesting the dominant adsorption of mango peel biochars is via monolayer adsorption. Biochar derived at 500 °C was found to have the highest adsorption capacity of 13.28 mg g-1 among all biochars and the adsorption efficiency was still 67.7% of the initial adsorption capacity after desorption for 4 times. Based on adsorption kinetics and isotherm analysis in combination with EDS, FTIR and XRD analysis, it was concluded that cation exchange, complexation with surface functional groups and precipitation with minerals were the dominant mechanisms responsible for Cd adsorption by mango peel biochar. The study suggested that mango peel can be recycled to biochars and can be used as a low-cost adsorbent for Cd(ii) removal from wastewater.