RESUMO
At present, Ni-based coatings are rarely used in the field of voltage control friction because of their poor antifriction, wear resistance, and conductive properties. Therefore, in this paper, Cu-BTC@Ag nanocrystals were used to enhance the nickel coatings, and the effect of voltage on their tribological properties was also investigated. It was found that the grains of coating were refined via the addition of Cu-BTC@Ag nanocrystals, leading to an improvement in the hardness and corrosion resistance of this composite coating. The tribological performance of nickel composite coating could be controlled under different electrical fields. With the comparison of the pure Ni-based coating, the average friction coefficient and wear volume of its composite coating with 5 wt % Cu-BTC@Ag were reduced by 7.0 and 91.8%, respectively, which showed excellent wear resistance without an applied voltage. Under the condition of 20 V, the 5 wt % Cu-BTC@Ag/Ni-based composite coating owned outstanding antifriction performance. Therefore, Cu-BTC@Ag played an intelligent role in regulating the friction of Ni-based coatings under an external voltage. It is due to the accumulation of Cu-BTC@Ag nanocrystals on the surface of the coating under the action of voltage, which played the role of supporting load and effectively reducing wear.
RESUMO
In order to develop an effective flame retardant for poly(vinyl chloride) (PVC), a core@double-shell structured magnesium hydroxide@9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide@melamine formaldehyde resin (MH@DOPO@ MF) encapsulated flame retardant was prepared. Its flame retardancy and smoke suppression effects in flexible PVC were investigated. Results show that the PVC/10 wt% MH@DOPO@MF composite has the best flame retardancy and smoke suppression performance in comparison with pure flexible PVC and the PVC/20 wt% MH composite. The limiting oxygen index (LOI) of the PVC/10 wt% MH@DOPO@MF composite was â¼30.8%, achieving a V-1 rating in the UL-94 test. MH@DOPO@MF in PVC remarkably increases the yields of the residual char and drastically decreased the heat release rate (HRR), total heat release (THR), smoke production rate (SPR) and total smoke production (TSP). The mechanical property testing showed that MH@DOPO@MF had slight damage on the tensile strength and elongation at break of PVC. This is ascribed to the synergistic flame-retardant effects of MH coordination with DOPO and MF. The present work demonstrates that the core@double-shell structured microcapsule (MH@DOPO@MF) prepared in this efficient manner has good flame retardancy and smoke suppression, and may provide a candidate flame retardant for applying in flexible PVC.
RESUMO
Highly exfoliated montmorillonite (MMT) clay reinforced thermoplastic polyurethane elastomers (TPUs) were prepared by an in situ solution polymerization method. By using small amount of 4,4'-methylenediphenyl diisocyanate (MDI) modified pristine clay (MDI-MMT) as fillers, the mechanical properties of TPUs were greatly improved. For example, with the addition of only 1.0 wt% of MDI-MMT, the resultant TPU/MDI-MMT nanocomposites showed approximately 36% increase in initial Young's modulus, 70% increase in tensile strength and 46% increase in ultimate elongation at break as compared with those of neat TPU. Detailed study showed that, owing to the strong covalent bonding between the MMT sheets and TPU matrix, MMT sheets were highly exfoliated during the polymerization process, and the highly exfoliated MMT sheets gave rise to the greatly improved mechanical properties and thermomechanical properties of TPU/MDI-MMT nanocomposites. The present work demonstrates that the in situ preparation of TPU/MDI-MMT nanocomposites by using MDI-MMT as fillers is a highly efficient method for reinforcing TPU.