Self-assembly of a lacunary alpha-Keggin undecatungstophosphate into a three-dimensional network linked by s-block cations.
Chem Commun (Camb)
; (23): 2896-7, 2002 Dec 07.
Article
in En
| MEDLINE
| ID: mdl-12478801
ABSTRACT
The crystal structure of [(CH3)4N]4Na2H[alpha-PW11O39].8H2O has been determined by using the Weissenberg camera at the BL04B2 beamline of SPring-8, revealing that it contains a disorder-free lacunary [alpha-PW11O39]7- anion with one sodium cation embedded into its lacuna that links the oxometalate building blocks into a one-dimensional chain, which is then woven into a three dimensional latticework by another Na+.
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Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Chem Commun (Camb)
Journal subject:
QUIMICA
Year:
2002
Type:
Article
Affiliation country:
Japan