Gas-phase isolation of diethyl guanosine 5'-monophosphate and its conformational assignment.
Phys Chem Chem Phys
; 12(42): 13918-21, 2010 Nov 14.
Article
in En
| MEDLINE
| ID: mdl-20859597
ABSTRACT
We show that intact neutral molecules of guanosine 5'-monophosphate can be vaporized by laser desorption when its phosphate group is esterified. The UV and IR spectroscopic measurements of this nucleotide reveal the existence of a novel internal hydrogen-bonding conformation of the phosphate group and guanine moiety.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Main subject:
Guanosine Monophosphate
/
Gases
/
Molecular Conformation
Language:
En
Journal:
Phys Chem Chem Phys
Journal subject:
BIOFISICA
/
QUIMICA
Year:
2010
Type:
Article
Affiliation country:
Japan