Magnesium-mediated arylation of amines via C-F bond activation of fluoroarenes.
Chem Commun (Camb)
; 55(30): 4339-4342, 2019 Apr 09.
Article
in En
| MEDLINE
| ID: mdl-30911746
ABSTRACT
A series of new Mg(ii) amides featuring a bulky ß-diketiminate backstop ligand, has been synthesised. These complexes are demonstrated to be excellent sources of nucleophilic amides that can participate in rapid C-F activation of several fluoroarenes at room temperature or using microwave assistance, leading to the installment of synthetically important C-N bonds via nucleophilic substitution.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Chem Commun (Camb)
Journal subject:
QUIMICA
Year:
2019
Type:
Article
Affiliation country:
United kingdom