Spontaneous Formation of a Cross-Linked Supramolecular Polymer Both in the Solid State and in Solution, Driven by Platinum(II) Metallacycle-Based Host-Guest Interactions.
J Am Chem Soc
; 141(16): 6494-6498, 2019 04 24.
Article
in En
| MEDLINE
| ID: mdl-30966741
ABSTRACT
The recent progress in platinum(II) coordination-driven supramolecular polymers has had a substantial effect on the design of functional soft materials. However, the prospect of realizing polymerization induced by platinum(II) metallacycle-based host-guest interactions has received little attention until recently. Here we report the realization of supramolecular polymerization driven by platinum(II) metallacycle-based host-guest interactions both in the solid state and in solution. On the basis of the disclosed polymerization mechanism, we present a new strategy for the preparation of platinum(II) metallacycle-based supramolecular polymers.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Main subject:
Platinum
/
Polymers
/
Coordination Complexes
Language:
En
Journal:
J Am Chem Soc
Year:
2019
Type:
Article
Affiliation country:
United States