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Spontaneous Formation of a Cross-Linked Supramolecular Polymer Both in the Solid State and in Solution, Driven by Platinum(II) Metallacycle-Based Host-Guest Interactions.
Shi, Bingbing; Liu, Yuezhou; Zhu, Huangtianzhi; Vanderlinden, Ryan T; Shangguan, Liqing; Ni, Ruidong; Acharyya, Koushik; Tang, Jian-Hong; Zhou, Zhixuan; Li, Xiaopeng; Huang, Feihe; Stang, Peter J.
Affiliation
  • Shi B; Department of Chemistry , University of Utah , 315 South 1400 East, Room 2020 , Salt Lake City , Utah 84112 , United States.
  • Liu Y; State Key Laboratory of Chemical Engineering, Center for Chemistry of High-Performance & Novel Materials, Department of Chemistry , Zhejiang University , Hangzhou 310027 , P. R. China.
  • Zhu H; State Key Laboratory of Chemical Engineering, Center for Chemistry of High-Performance & Novel Materials, Department of Chemistry , Zhejiang University , Hangzhou 310027 , P. R. China.
  • Vanderlinden RT; Department of Chemistry , University of Utah , 315 South 1400 East, Room 2020 , Salt Lake City , Utah 84112 , United States.
  • Shangguan L; State Key Laboratory of Chemical Engineering, Center for Chemistry of High-Performance & Novel Materials, Department of Chemistry , Zhejiang University , Hangzhou 310027 , P. R. China.
  • Ni R; Department of Chemistry , University of South Florida , 4202 East Fowler Avenue , Tampa , Florida 33620 , United States.
  • Acharyya K; Department of Chemistry , University of Utah , 315 South 1400 East, Room 2020 , Salt Lake City , Utah 84112 , United States.
  • Tang JH; Department of Chemistry , University of Utah , 315 South 1400 East, Room 2020 , Salt Lake City , Utah 84112 , United States.
  • Zhou Z; Department of Chemistry , University of Utah , 315 South 1400 East, Room 2020 , Salt Lake City , Utah 84112 , United States.
  • Li X; Department of Chemistry , University of South Florida , 4202 East Fowler Avenue , Tampa , Florida 33620 , United States.
  • Huang F; State Key Laboratory of Chemical Engineering, Center for Chemistry of High-Performance & Novel Materials, Department of Chemistry , Zhejiang University , Hangzhou 310027 , P. R. China.
  • Stang PJ; Department of Chemistry , University of Utah , 315 South 1400 East, Room 2020 , Salt Lake City , Utah 84112 , United States.
J Am Chem Soc ; 141(16): 6494-6498, 2019 04 24.
Article in En | MEDLINE | ID: mdl-30966741
ABSTRACT
The recent progress in platinum(II) coordination-driven supramolecular polymers has had a substantial effect on the design of functional soft materials. However, the prospect of realizing polymerization induced by platinum(II) metallacycle-based host-guest interactions has received little attention until recently. Here we report the realization of supramolecular polymerization driven by platinum(II) metallacycle-based host-guest interactions both in the solid state and in solution. On the basis of the disclosed polymerization mechanism, we present a new strategy for the preparation of platinum(II) metallacycle-based supramolecular polymers.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Platinum / Polymers / Coordination Complexes Language: En Journal: J Am Chem Soc Year: 2019 Type: Article Affiliation country: United States
Fulltext
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Platinum / Polymers / Coordination Complexes Language: En Journal: J Am Chem Soc Year: 2019 Type: Article Affiliation country: United States