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Precise Self-Assembly of Molecular Four- and Six-Pointed Stars.
Jiang, Zhiyuan; Xue, Xiaobo; Wu, Tun; Chen, Mingzhao; Wang, Shi-Cheng; Wang, Jun; Yan, Jun; Chan, Yi-Tsu; Wang, Pingshan.
Affiliation
  • Jiang Z; Department of Organic and Polymer Chemistry, College of Chemistry and Chemical Engineering , Central South University , Changsha , Hunan 410083 , China.
  • Xue X; Department of Organic and Polymer Chemistry, College of Chemistry and Chemical Engineering , Central South University , Changsha , Hunan 410083 , China.
  • Wu T; Institute of Environmental Research at Greater Bay Area; Key Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education ; Guangzhou University , Guangzhou 510006 , China.
  • Chen M; Department of Organic and Polymer Chemistry, College of Chemistry and Chemical Engineering , Central South University , Changsha , Hunan 410083 , China.
  • Wang SC; Department of Chemistry , National Taiwan University , Taipei 10617 , Taiwan.
  • Wang J; Department of Organic and Polymer Chemistry, College of Chemistry and Chemical Engineering , Central South University , Changsha , Hunan 410083 , China.
  • Yan J; Department of Organic and Polymer Chemistry, College of Chemistry and Chemical Engineering , Central South University , Changsha , Hunan 410083 , China.
  • Chan YT; Department of Chemistry , National Taiwan University , Taipei 10617 , Taiwan.
  • Wang P; Department of Organic and Polymer Chemistry, College of Chemistry and Chemical Engineering , Central South University , Changsha , Hunan 410083 , China.
Inorg Chem ; 59(1): 875-879, 2020 Jan 06.
Article in En | MEDLINE | ID: mdl-31868353
ABSTRACT
A novel metal-organic ligand (MOL 2) has been prepared by linking two V-shaped bis-terpyridines with one X-shaped tetrakis-terpyridine through the stable connectivity. The complexation between MOL 2, X-shaped tetrakis-terpyridine, and Zn2+ gave rise to a supramolecular C6-symmetrical six-pointed star quantitatively. In addition, a mixture of MOL 2, K-shaped tetrakis-terpyridine, and Zn2+ afforded a C2-symmetrical four-pointed star. These metallo-supramolecular architectures were adequately characterized by NMR, ESI-MS, TWIM-MS, and TEM analyses.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Inorg Chem Year: 2020 Type: Article Affiliation country: China
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Inorg Chem Year: 2020 Type: Article Affiliation country: China