Incorporation of a Cp*Rh(III)-dithiophosphate Cofactor with Latent Activity into a Protein Scaffold Generates a Biohybrid Catalyst Promoting C(sp<sup>2</sup>)-H Bond Functionalization.

Kato, Shunsuke; Onoda, Akira; Grimm, Alexander R; Tachikawa, Kengo; Schwaneberg, Ulrich; Hayashi, Takashi

Incorporation of a Cp*Rh(III)-dithiophosphate Cofactor with Latent Activity into a Protein Scaffold Generates a Biohybrid Catalyst Promoting C(sp²)-H Bond Functionalization.

Kato, Shunsuke; Onoda, Akira; Grimm, Alexander R; Tachikawa, Kengo; Schwaneberg, Ulrich; Hayashi, Takashi.

Affiliation

Kato S; Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita 565-0871, Japan.
Onoda A; Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita 565-0871, Japan.
Grimm AR; Institute of Biotechnology, RWTH Aachen University, Worringerweg 3, 52074 Aachen, Germany.
Tachikawa K; Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita 565-0871, Japan.
Schwaneberg U; Institute of Biotechnology, RWTH Aachen University, Worringerweg 3, 52074 Aachen, Germany.
Hayashi T; Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita 565-0871, Japan.

Inorg Chem ; 59(19): 14457-14463, 2020 Oct 05.

Article in En | MEDLINE | ID: mdl-32914980

Subject(s)

Biomimetic Materials/chemistry; Carbon/chemistry; Coordination Complexes/chemistry; Hydrogen/chemistry; Phosphates/chemistry; Proteins/chemistry; Rhodium/chemistry; Catalysis; Oximes/chemistry; Silver/chemistry

Fulltext

XML

PubMed Links

Search on Google

Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Phosphates / Rhodium / Carbon / Proteins / Biomimetic Materials / Coordination Complexes / Hydrogen Language: En Journal: Inorg Chem Year: 2020 Type: Article Affiliation country: Japan

Fulltext

XML

PubMed Links

Search on Google