Highly Efficient and Chemoselective Hydrogenation of Nitro Compounds into Amines by Nitrogen-Doped Porous Carbon-Supported Co/Ni Bimetallic Nanoparticles.
Inorg Chem
; 60(21): 16834-16839, 2021 Nov 01.
Article
in En
| MEDLINE
| ID: mdl-34693707
ABSTRACT
A novel Co/Ni bimetallic nanoparticle supported by nitrogen-doped porous carbon (NPC), Co5/Ni@NPC-700, exhibits high conversion, chemoselectivity, and recyclability in the hydrogenation of 16 different nitro compounds into desired amines with hydrazine hydrate under mild conditions. The synergistic effects of Co/Ni bimetal nanoparticles and the NPC-supported porous honeycomb structure with more accessible active sites may be responsible for the high catalytic hydrogenation performance.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Inorg Chem
Year:
2021
Type:
Article