Your browser doesn't support javascript.
loading
Templation and Concentration Drive Conversion Between a FeII12L12 Pseudoicosahedron, a FeII4L4 Tetrahedron, and a FeII2L3 Helicate.
Zhang, Dawei; Gan, Quan; Plajer, Alex J; Lavendomme, Roy; Ronson, Tanya K; Lu, Zifei; Jensen, Jesper D; Laursen, Bo W; Nitschke, Jonathan R.
Affiliation
  • Zhang D; Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, People's Republic of China.
  • Gan Q; Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB2 1EW, United Kingdom.
  • Plajer AJ; Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB2 1EW, United Kingdom.
  • Lavendomme R; Hubei Key Laboratory of Bioinorganic Chemistry & Materia Medica, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, People's Republic of China.
  • Ronson TK; Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB2 1EW, United Kingdom.
  • Lu Z; Oxford Chemistry, Chemical Research Laboratory, 12 Mansfield Road, Oxford, OX1 3TA, U.K.
  • Jensen JD; COMOC─Center for Ordered Materials, Organometallics and Catalysis, Department of Chemistry, Ghent University, Krijgslaan 281-S3, 9000 Ghent, Belgium.
  • Laursen BW; Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB2 1EW, United Kingdom.
  • Nitschke JR; Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB2 1EW, United Kingdom.
J Am Chem Soc ; 144(3): 1106-1112, 2022 01 26.
Article in En | MEDLINE | ID: mdl-35014803
We report the construction of three structurally distinct self-assembled architectures: FeII12L12 pseudoicosahedron 1, FeII2L3 helicate 2, and FeII4L4 tetrahedron 3, formed from a single triazatriangulenium subcomponent A under different reaction conditions. Pseudoicosahedral capsule 1 is the largest formed through subcomponent self-assembly to date, with an outer-sphere diameter of 5.4 nm and a cavity volume of 15 nm3. The outcome of self-assembly depended upon concentration, where the formation of pseudoicosahedron 1 was favored at higher concentrations, while helicate 2 exclusively formed at lower concentrations. The conversion of pseudoicosahedron 1 or helicate 2 into tetrahedron 3 occurred following the addition of a CB11H12- or B12F122- template.
Fulltext
Print
XML
PubMed Links
Search on Google

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: J Am Chem Soc Year: 2022 Type: Article
Fulltext
Print
XML
PubMed Links
Search on Google

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: J Am Chem Soc Year: 2022 Type: Article