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Palladium-Catalyzed Silylacylation of Allenes Using Acylsilanes.
Inagaki, Tetsuya; Sakurai, Shun; Yamanaka, Masahiro; Tobisu, Mamoru.
Affiliation
  • Inagaki T; Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka, 565-0871, Japan.
  • Sakurai S; Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka, 565-0871, Japan.
  • Yamanaka M; Department of Chemistry and Research Center for Smart Molecules, Faculty of Science, Rikkyo University, Nishi-Ikebukuro, Toshima-ku, Tokyo, 171-8501, Japan.
  • Tobisu M; Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka, 565-0871, Japan.
Angew Chem Int Ed Engl ; 61(21): e202202387, 2022 May 16.
Article in En | MEDLINE | ID: mdl-35263006
We have developed a palladium-catalyzed addition of a C-Si bond of acylsilanes across a range of unactivated allenes. The reaction proceeds with complete regioselectivity, in which a silyl group binds to the central carbon of the allene, allowing for the straightforward access to functionalized alkenylsilane derivatives.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Angew Chem Int Ed Engl Year: 2022 Type: Article Affiliation country: Japan
Fulltext
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PubMed Links
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Angew Chem Int Ed Engl Year: 2022 Type: Article Affiliation country: Japan