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A Ratiometric Fluorescent Sensor Based on Dye/Tb (III) Functionalized UiO-66 for Highly Sensitive Detection of TDGA.
Fan, Yangchun; Jiang, Xin; Che, Jie; Li, Mingfeng; Zhang, Xuejuan; Gao, Daojiang; Bi, Jian; Ning, Zhanglei.
Affiliation
  • Fan Y; College of Chemistry and Materials Science, Sichuan Normal University, Chengdu 610068, China.
  • Jiang X; College of Chemistry and Materials Science, Sichuan Normal University, Chengdu 610068, China.
  • Che J; College of Chemistry and Materials Science, Sichuan Normal University, Chengdu 610068, China.
  • Li M; College of Chemistry and Materials Science, Sichuan Normal University, Chengdu 610068, China.
  • Zhang X; The Experiment Center, Shandong Police College, Ji'nan 250014, China.
  • Gao D; College of Chemistry and Materials Science, Sichuan Normal University, Chengdu 610068, China.
  • Bi J; College of Chemistry and Materials Science, Sichuan Normal University, Chengdu 610068, China.
  • Ning Z; College of Chemistry and Materials Science, Sichuan Normal University, Chengdu 610068, China.
Molecules ; 27(19)2022 Oct 03.
Article in En | MEDLINE | ID: mdl-36235080
ABSTRACT
Thiodiglycolic acid (TDGA) is a biomarker for monitoring vinyl chloride exposure. Exploring a facile, rapid and precise analysis technology to quantify TDGA is of great significance. In this research, we demonstrate a fluorescent sensor based on dual-emissive UiO-66 for TDGA detection. This ratiometric fluorescent material named C460@Tb-UiO-66-(COOH)2 was designed and synthesized by introducing organic dye 7-diethylamino-4-methylcoumarin (C460) and Tb3+ into UiO-66-(COOH)2. The as-obtained C460@Tb-UiO-66-(COOH)2 samples showed highly selective recognition, excellent anti-interference and rapid response characteristics for the recognition of TDGA. The detection limit is 0.518 mg·mL-1, which is much lower than the threshold of 20 mg·mL-1 for a healthy person. In addition, the mechanism of TDGA-induced fluorescence quenching is discussed in detail. This sensor is expected to detect TDGA content in human urine.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Vinyl Chloride Type of study: Diagnostic_studies Limits: Humans Language: En Journal: Molecules Journal subject: BIOLOGIA Year: 2022 Type: Article Affiliation country: China
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Vinyl Chloride Type of study: Diagnostic_studies Limits: Humans Language: En Journal: Molecules Journal subject: BIOLOGIA Year: 2022 Type: Article Affiliation country: China