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Biomimetic models of [Fe]-hydrogenase featuring a 2-acylphenylthiomethyl-6-R-pyridine (R = H or OMe) ligand.
Song, Li-Cheng; Zhang, Zhen-Qing; Liu, Bei-Bei; Wang, Yin-Peng; Chen, Shuai.
Affiliation
  • Song LC; Department of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071, China. lcsong@nankai.edu.cn.
  • Zhang ZQ; Department of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071, China. lcsong@nankai.edu.cn.
  • Liu BB; Department of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071, China. lcsong@nankai.edu.cn.
  • Wang YP; Department of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071, China. lcsong@nankai.edu.cn.
  • Chen S; Department of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071, China. lcsong@nankai.edu.cn.
Chem Commun (Camb) ; 58(87): 12168-12171, 2022 Nov 01.
Article in En | MEDLINE | ID: mdl-36239209
ABSTRACT
Despite a variety of [Fe]-H2ase models prepared so far, the structural and functional modeling study of the enzyme has remained a great challenge. Now, we report a new type of flexible pyridine ligand (FPL)-based synthetic method by which two novel [Fe]-H2ase models have been prepared. Notably, the two models contain not only a biomimetic fac-acyl C, pyridyl N, thioether S coordination mode but also possess the enzyme-like H2/D2 activation functions.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Biomimetic Materials / Hydrogenase / Iron-Sulfur Proteins Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2022 Type: Article Affiliation country: China
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Biomimetic Materials / Hydrogenase / Iron-Sulfur Proteins Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2022 Type: Article Affiliation country: China