Periodic Trends in the Infrared and Optical Absorption Spectra of Metal Chalcogenide Clusters.

ABSTRACT

We have investigated the optical absorption, infrared spectra, binding energies, and other cluster properties to investigate whether periodic trends can be observed in the electronic structure of transition metal chalcogenide clusters ligated with CO ligands. Our studies demonstrate the existence of several periodic trends in the properties of pure and mixed octahedral metal chalcogenide clusters, TM6Se8(CO)6 (TM = W-Pt). We find that octahedral metal chalcogenide clusters with 96, 100, and 114 valence electrons have larger excitation energies, consistent with these clusters having closed electronic shells. Periodic trends were observed in the infrared spectra, with the CO bond stretch having the highest energy at 100 and 114 valence electrons due to the closed electronic shell minimizing back-bonding with the CO molecule. A periodic trend in the antisymmetric TM-C stretch was also observed, with the vibrational energy increasing as the valence electron count increased. This is due to decrease in the TM-C bond length, resulting in a larger force constant. These results reveal that periodic trends seen earlier in simple or noble-metal clusters can be observed in symmetric transition metal chalcogenide clusters, showing that the superatom concept in metal chalcogenide clusters goes beyond electronic excitations, and can be seen in other observable properties.