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Thermal batteries based on inverse barocaloric effects.
Zhang, Zhe; Li, Kuo; Lin, Shangchao; Song, Ruiqi; Yu, Dehong; Wang, Yida; Wang, Jingfan; Kawaguchi, Shogo; Zhang, Zhao; Yu, Chenyang; Li, Xiaodong; Chen, Jie; He, Lunhua; Mole, Richard; Yuan, Bao; Ren, Qingyong; Qian, Kun; Cai, Zhuangli; Yu, Jingui; Wang, Mingchao; Zhao, Changying; Tong, Xin; Zhang, Zhidong; Li, Bing.
Affiliation
  • Zhang Z; Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang, Liaoning 110016, China.
  • Li K; School of Materials Science and Engineering, University of Science and Technology of China, 72 Wenhua Road, Shenyang, Liaoning 110016, China.
  • Lin S; Center for High Pressure Science and Technology Advanced Research, Beijing 100193, China.
  • Song R; Key Laboratory for Power Machinery and Engineering of Ministry of Education, Institute of Engineering Thermophysics, School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China.
  • Yu D; Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang, Liaoning 110016, China.
  • Wang Y; Australian Nuclear Science and Technology Organisation, Locked Bag 2001, Kirrawee DC, NSW 2232, Australia.
  • Wang J; Center for High Pressure Science and Technology Advanced Research, Beijing 100193, China.
  • Kawaguchi S; Department of Mechanical Engineering, Florida State University, Tallahassee, FL 32310, USA.
  • Zhang Z; Japan Synchrotron Radiation Research Institute, SPring-8, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198, Japan.
  • Yu C; Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang, Liaoning 110016, China.
  • Li X; School of Materials Science and Engineering, University of Science and Technology of China, 72 Wenhua Road, Shenyang, Liaoning 110016, China.
  • Chen J; Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang, Liaoning 110016, China.
  • He L; School of Materials Science and Engineering, University of Science and Technology of China, 72 Wenhua Road, Shenyang, Liaoning 110016, China.
  • Mole R; Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China.
  • Yuan B; Spallation Neutron Source Science Center, Dongguan 523803, China.
  • Ren Q; Spallation Neutron Source Science Center, Dongguan 523803, China.
  • Qian K; Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China.
  • Cai Z; Songshan Lake Materials Laboratory, Dongguan 523808, China.
  • Yu J; Australian Nuclear Science and Technology Organisation, Locked Bag 2001, Kirrawee DC, NSW 2232, Australia.
  • Wang M; Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China.
  • Zhao C; Spallation Neutron Source Science Center, Dongguan 523803, China.
  • Tong X; Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China.
  • Zhang Z; Spallation Neutron Source Science Center, Dongguan 523803, China.
  • Li B; Key Laboratory for Power Machinery and Engineering of Ministry of Education, Institute of Engineering Thermophysics, School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China.
Sci Adv ; 9(7): eadd0374, 2023 Feb 17.
Article in En | MEDLINE | ID: mdl-36800425
ABSTRACT
To harvest and reuse low-temperature waste heat, we propose and realize an emergent concept-barocaloric thermal batteries based on the large inverse barocaloric effect of ammonium thiocyanate (NH4SCN). Thermal charging is initialized upon pressurization through an order-to-disorder phase transition, and the discharging of 43 J g-1 takes place at depressurization, which is 11 times more than the input mechanical energy. The thermodynamic equilibrium nature of the pressure-restrained heat-carrying phase guarantees stable long-duration storage. The barocaloric thermal batteries reinforced by their solid microscopic mechanism are expected to substantially advance the ability to take advantage of waste heat.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Sci Adv Year: 2023 Type: Article Affiliation country: China
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PubMed Links
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Sci Adv Year: 2023 Type: Article Affiliation country: China