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Facile preparation of optically active helical polycarbenes with salicylate substituents and their postpolymerization modification.
Zou, Hui; Tai, Shan; Zhao, Shu-Yang; Zhou, Li; Liu, Na; Wu, Zong-Quan.
Affiliation
  • Zou H; Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei, Anhui Province 230009, China. zouh@huft.edu.cn.
  • Tai S; Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei, Anhui Province 230009, China. zouh@huft.edu.cn.
  • Zhao SY; Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei, Anhui Province 230009, China. zouh@huft.edu.cn.
  • Zhou L; Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei, Anhui Province 230009, China. zouh@huft.edu.cn.
  • Liu N; The School of Pharmaceutical Sciences, Jilin University, 1266 Fujin Road, Changchun, Jilin Province 130021, China. liuna606@jlu.edu.cn.
  • Wu ZQ; State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, China. zqwu@jlu.edu.cn.
Chem Commun (Camb) ; 59(28): 4201-4204, 2023 Apr 04.
Article in En | MEDLINE | ID: mdl-36938750
ABSTRACT
Optically active helical polycarbenes were constructed through the living and controlled helix-sense-selective polymerization (HSSP) of methyl salicylate modified diazoacetate monomer catalysed via π-allylPdCl with chiral phosphine ligands. The obtained helical polycarbenes could undergo postpolymerization modification to afford functional polycarbenes efficiently.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2023 Type: Article Affiliation country: China
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2023 Type: Article Affiliation country: China