Broken bond models, magic-sized clusters, and nucleation theory in nanoparticle synthesis.
J Chem Phys
; 158(11): 114306, 2023 Mar 21.
Article
in En
| MEDLINE
| ID: mdl-36948834
ABSTRACT
Magic clusters are metastable faceted nanoparticles that are thought to be important and, sometimes, observable intermediates in the nucleation of certain faceted crystallites. This work develops a broken bond model for spheres with a face-centered-cubic packing that form tetrahedral magic clusters. With just one bond strength parameter, statistical thermodynamics yield a chemical potential driving force, an interfacial free energy, and free energy vs magic cluster size. These properties exactly correspond to those from a previous model by Mule et al. [J. Am. Chem. Soc. 143, 2037 (2021)]. Interestingly, a Tolman length emerges (for both models) when the interfacial area, density, and volume are treated consistently. To describe the kinetic barriers between magic cluster sizes, Mule et al. invoked an energy parameter to penalize the two-dimensional nucleation and growth of new layers in each facet of the tetrahedra. According to the broken bond model, barriers between magic clusters are insignificant without the additional edge energy penalty. We estimate the overall nucleation rate without predicting the rates of formation for intermediate magic clusters by using the Becker-Döring equations. Our results provide a blueprint for constructing free energy models and rate theories for nucleation via magic clusters starting from only atomic-scale interactions and geometric considerations.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Type of study:
Prognostic_studies
Language:
En
Journal:
J Chem Phys
Year:
2023
Type:
Article
Affiliation country:
United States