Many-Body Description of STM-Induced Fluorescence of Charged Molecules.
Phys Rev Lett
; 130(12): 126202, 2023 Mar 24.
Article
in En
| MEDLINE
| ID: mdl-37027885
ABSTRACT
A scanning tunneling microscope is used to study the fluorescence of a model charged molecule (quinacridone) adsorbed on a sodium chloride (NaCl)-covered metallic sample. Fluorescence from the neutral and positively charged species is reported and imaged using hyperresolved fluorescence microscopy. A many-body model is established based on a detailed analysis of voltage, current, and spatial dependences of the fluorescence and electron transport features. This model reveals that quinacridone adopts a palette of charge states, transient or not, depending on the voltage used and the nature of the underlying substrate. This model has a universal character and clarifies the transport and fluorescence mechanisms of molecules adsorbed on thin insulators.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Phys Rev Lett
Year:
2023
Type:
Article
Affiliation country:
France