Synthesis, Structure, and Reactivity of a Gallylene Derivative Bearing a Phenalenyl-Based Ligand.
Inorg Chem
; 62(17): 6554-6559, 2023 May 01.
Article
in En
| MEDLINE
| ID: mdl-37074144
ABSTRACT
Phenalenyl-based N,N-bidentate ligand-stabilized monovalent gallium(I) complex 1 was synthesized and characterized by NMR spectroscopies, single-crystal X-ray diffraction, and theoretical calculations. In solution, complex 1 has a high thermal stability at 80 °C, with an absorption maximum at 505 nm. Complex 1 promotes the oxidative addition of I-I, Si-Cl, C-I, and S-S bonds and oxidative cyclization with various π components. Complex 1 can also coordinate to a tungsten complex to form a Ga-W bond.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Inorg Chem
Year:
2023
Type:
Article
Affiliation country:
Japan