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Efficient separation of monobromotoluene isomers by nonporous adaptive perbromoethylated pillar[5]arene crystals.
Zhao, Bohan; Wang, Jianwei; Shao, Li; Wu, Yitao; Li, Ming; Hua, Bin; Huang, Feihe.
Affiliation
  • Zhao B; Stoddart Institute of Molecular Science, Department of Chemistry, Zhejiang University, Hangzhou 310058, P. R. China. mingzhelee@zju.edu.cn.
  • Wang J; Stoddart Institute of Molecular Science, Department of Chemistry, Zhejiang University, Hangzhou 310058, P. R. China. mingzhelee@zju.edu.cn.
  • Shao L; Zhejiang-Israel Joint Laboratory of Self-Assembling Functional Materials, ZJU-Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou 311215, P. R. China.
  • Wu Y; Department of Materials Science and Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, P. R. China.
  • Li M; Stoddart Institute of Molecular Science, Department of Chemistry, Zhejiang University, Hangzhou 310058, P. R. China. mingzhelee@zju.edu.cn.
  • Hua B; Stoddart Institute of Molecular Science, Department of Chemistry, Zhejiang University, Hangzhou 310058, P. R. China. mingzhelee@zju.edu.cn.
  • Huang F; Stoddart Institute of Molecular Science, Department of Chemistry, Zhejiang University, Hangzhou 310058, P. R. China. mingzhelee@zju.edu.cn.
Chem Commun (Camb) ; 59(69): 10432-10435, 2023 Aug 24.
Article in En | MEDLINE | ID: mdl-37555311
Herein we report an efficient adsorptive separation approach for monobromotoluene isomers using nonporous adaptive crystals of perbromoethylated pillar[5]arene (BrP5). The purity of separated m-bromotoluene from an equal volume mixture of m-bromotoluene and o-bromotoluene reaches 96.6% in one cycle and the adsorbent BrP5 can be reused without losing separation performance.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2023 Type: Article
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2023 Type: Article