A Silver Nanocluster Assembled by a Superatomic Building Unit.
Inorg Chem
; 63(12): 5320-5324, 2024 Mar 25.
Article
in En
| MEDLINE
| ID: mdl-38468603
ABSTRACT
A unique assembly of a two-electron superatom, [Ag10{S2P(OiPr)2}8], as a primary building unit in the construction of a supramolecule [Ag10{S2P(OiPr)2}8]2(µ-4,4'-bpy) through a 4,4'-bipyridine (4,4'-bpy) linker is reported. This approach is facilitated by an open site in the structure that allows for effective pairing. The assembled structure demonstrates a minimal solvatochromic shift across organic solvents with variable polarities, highlighting the influence of self-assembly on the photophysical properties of silver nanoclusters.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Inorg Chem
/
Inorg. chem
/
Inorganic chemistry
Year:
2024
Type:
Article
Affiliation country:
China