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Elevating the Performance of Heterometallic 3d/4f SMMs: The Role of Diamagnetic CoIII and ZnII Ions in Magnetization Dynamics.
Vignesh, Kuduva R; Armenis, Alexandros S; Alexandropoulos, Dimitris I; Stamatatos, Theocharis C.
Affiliation
  • Vipanchi; Department of Chemical Sciences, Indian Institute of Science Education and Research (IISER) Mohali, Sector-81, Knowledge city, S.A.S. Nagar, Mohali, Punjab, 140306, India.
  • Vignesh KR; Department of Chemical Sciences, Indian Institute of Science Education and Research (IISER) Mohali, Sector-81, Knowledge city, S.A.S. Nagar, Mohali, Punjab, 140306, India.
  • Armenis AS; Department of Chemistry, University of Patras, 265 04, Patras, Greece.
  • Alexandropoulos DI; Department of Chemistry, University of Patras, 265 04, Patras, Greece.
  • Stamatatos TC; Department of Chemistry, University of Patras, 265 04, Patras, Greece.
Chemphyschem ; : e202400385, 2024 Jun 18.
Article in En | MEDLINE | ID: mdl-38890803
ABSTRACT
Recent advances in the synthesis of 3d/4f Single-Molecule Magnets (SMMs) have revealed the effective role of incorporating diamagnetic CoIII or ZnII ions to enhance the magnetic properties of LnIII ions. This concept highlights notable examples of CoIII/LnIII and ZnII/LnIII SMMs documented in the recent literature, illustrating how the selection of various peripheral and/or bridging ligands can modulate the magnetic anisotropy of 4f metal ions, thereby increasing their energy barriers.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: ChemPhysChem (Internet) / Chemphyschem Journal subject: BIOFISICA / QUIMICA Year: 2024 Type: Article Affiliation country: India
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: ChemPhysChem (Internet) / Chemphyschem Journal subject: BIOFISICA / QUIMICA Year: 2024 Type: Article Affiliation country: India