Cerium(IV) tellurite halides [Ce2Te7O17]X2 (X = Cl- or Br-): the first cerium-containing cationic frameworks.
Inorg Chem
; 51(19): 10083-5, 2012 Oct 01.
Article
em En
| MEDLINE
| ID: mdl-22991994
ABSTRACT
Two isotypic cerium tellurite halides with the formulas [Ce(2)Te(7)O(17)]Cl(2) and [Ce(2)Te(7)O(17)]Br(2) have been synthesized hydrothermally via the reactions of CeCl(3) and CeBr(3) with TeO(2). The structures of these compounds feature a cationic inorganic framework. The Ce(IV) dimers are bound by a novel 3D Te(7)O(17)(6-) building unit, forming an unusual hexagonal-bipyramidal environment around Ce(IV).
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01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Inorg Chem
Ano de publicação:
2012
Tipo de documento:
Article
País de afiliação:
Estados Unidos