Two Reaction Mechanisms via Iminium Ion Intermediates: The Different Reactivities of Diphenylprolinol Silyl Ether and Trifluoromethyl-Substituted Diarylprolinol Silyl Ether.

Gotoh, Hiroaki; Uchimaru, Tadafumi; Hayashi, Yujiro

Gotoh, Hiroaki; Uchimaru, Tadafumi; Hayashi, Yujiro.

Afiliação

Gotoh H; Department of Applied Chemistry, Yokohama National University, 79-5 Tokiwadai, Hodogayaku, Yokohama 240-8501 (Japan).
Uchimaru T; Research Institute for Sustainable Chemistry, National Institute of Advanced Industrial Science and Technology, Tsukuba, Ibaraki 305-8565 (Japan).
Hayashi Y; Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aramaki-Aza Aoba, Aoba-ku, Sendai 980-8578 (Japan) http://www.ykbsc-chem.com. yhayashi@m.tohoku.ac.jp.

Chemistry ; 21(35): 12337-46, 2015 Aug 24.

Article em En | MEDLINE | ID: mdl-26096559

Palavras-chave

asymmetric synthesis; iminium ions; organocatalysis; reaction mechanisms; silyl ethers

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chemistry Assunto da revista: QUIMICA Ano de publicação: 2015 Tipo de documento: Article

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