How Does Substitutional Doping Affect Visible Light Absorption in a Series of Homodisperse Ti11 Polyoxotitanate Nanoparticles--A Comment on the Band Gap Determination of the Fe(II) Cages (Chem. Eur. J. 2015, 21, 11538).

Matthews, Peter D; Li, Ning; Luo, He-Kuan; Wright, Dominic S

Matthews, Peter D; Li, Ning; Luo, He-Kuan; Wright, Dominic S.

Afiliação

Matthews PD; Chemistry Department, Cambridge University, Lensfield Road, Cambridge, UK.
Li N; Chemistry Department, Cambridge University, Lensfield Road, Cambridge, UK.
Luo HK; Institute of Materials Research and Engineering, Agency for Science, Technology and Research, 2 Fusionopolis Way, #08-03, Innovis, Singapore, 138634, Singapore.
Wright DS; Institute of Materials Research and Engineering, Agency for Science, Technology and Research, 2 Fusionopolis Way, #08-03, Innovis, Singapore, 138634, Singapore.

Chemistry ; 22(13): 4632-3, 2016 Mar 18.

Article em En | MEDLINE | ID: mdl-26929058

ABSTRACT

ABSTRACT

There is no experimental support for the conclusion by Coppens and Chen in a recent paper that the (HOMO-LUMO) band gaps in a series of Fe(II) polyoxotitanate cages are in the range 1.43-1.59 eV.

Palavras-chave

UV/Vis spectroscopy; band gap determination; iron; polyoxotitanate

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chemistry Assunto da revista: QUIMICA Ano de publicação: 2016 Tipo de documento: Article País de afiliação: Reino Unido

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