Insight into the deprotonation at the half-equivalence point of (thio)amido-benzimidazoles in the presence of anions.

Koeller, S; Lescure, M-H; Davies, C; Desvergne, J-P; Massip, S; Bibal, B

Koeller, S; Lescure, M-H; Davies, C; Desvergne, J-P; Massip, S; Bibal, B.

Afiliação

Koeller S; Université de Bordeaux, Institut des Sciences Moléculaires UMR 5255, 351 cours de la Libération, 33405 Talence, France. brigitte.bibal@u-bordeaux.fr.

Org Biomol Chem ; 15(35): 7263-7266, 2017 Sep 13.

Article em En | MEDLINE | ID: mdl-28832051

ABSTRACT

ABSTRACT

Three crystallographic structures highlight the acid-base half-equivalence point of hydrogen-bond donor (thio)amido-benzimidazoles induced by fluoride or benzoate salts with concomitant hydrogen-bonding and deprotonation as a merged synergic process.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Org Biomol Chem Assunto da revista: BIOQUIMICA / QUIMICA Ano de publicação: 2017 Tipo de documento: Article País de afiliação: França

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