A versatile synthetic route for the preparation of titanium metal-organic frameworks.
Chem Sci
; 7(2): 1063-1069, 2016 Feb 01.
Article
em En
| MEDLINE
| ID: mdl-29896371
ABSTRACT
Exploitation of new titanium metal-organic frameworks (Ti-MOFs) with high crystallinity has been attracting great attention due to their vast application potential in photocatalysis. Herein a versatile synthetic strategy, namely, High Valence Metathesis and Oxidation (HVMO), is developed to synthesize a series of Ti-MOFs with predesigned topologies and structures. The crystallinity of these Ti-MOFs was well maintained throughout, as confirmed by powder X-ray diffraction and gas adsorption measurements. Significantly, there were only a few examples of Ti-MOFs, not to mention a general synthetic strategy for various kinds of Ti-MOFs in the literature. This contribution also illustrates the intriguing potential of Ti-MOF platforms in photocatalysis.
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01-internacional
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MEDLINE
Idioma:
En
Revista:
Chem Sci
Ano de publicação:
2016
Tipo de documento:
Article