Your browser doesn't support javascript.
loading
Design Rules for Self-Assembly of 2D Nanocrystal/Metal-Organic Framework Superstructures.
Qiu, Fen; Edison, John R; Preisler, Zdenek; Zhang, Yan-Fang; Li, Guo; Pan, Aizhao; Hsu, Chih-Hao; Mattox, Tracy M; Ercius, Peter; Song, Chengyu; Bustillo, Karen; Brady, Michael A; Zaia, Edmond W; Jeong, Sohee; Neaton, Jeffrey B; Du, Shixuan; Whitelam, Stephen; Urban, Jeffrey J.
Afiliação
  • Qiu F; The Molecular Foundry, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA, 94720, USA.
  • Edison JR; The Molecular Foundry, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA, 94720, USA.
  • Preisler Z; The Molecular Foundry, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA, 94720, USA.
  • Zhang YF; Institute of Physics &, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing, 100190, China.
  • Li G; The Molecular Foundry, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA, 94720, USA.
  • Pan A; The Molecular Foundry, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA, 94720, USA.
  • Hsu CH; The Molecular Foundry, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA, 94720, USA.
  • Mattox TM; The Molecular Foundry, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA, 94720, USA.
  • Ercius P; National Center for Electron Microscopy, The Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, CA, 94720, USA.
  • Song C; National Center for Electron Microscopy, The Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, CA, 94720, USA.
  • Bustillo K; National Center for Electron Microscopy, The Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, CA, 94720, USA.
  • Brady MA; Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA, 94720, USA.
  • Zaia EW; The Molecular Foundry, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA, 94720, USA.
  • Jeong S; The Molecular Foundry, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA, 94720, USA.
  • Neaton JB; The Molecular Foundry, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA, 94720, USA.
  • Du S; Institute of Physics &, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing, 100190, China.
  • Whitelam S; The Molecular Foundry, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA, 94720, USA.
  • Urban JJ; The Molecular Foundry, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA, 94720, USA.
Angew Chem Int Ed Engl ; 57(40): 13172-13176, 2018 Oct 01.
Article em En | MEDLINE | ID: mdl-30136423
ABSTRACT
We demonstrate the guiding principles behind simple two dimensional self-assembly of MOF nanoparticles (NPs) and oleic acid capped iron oxide (Fe3 O4 ) NCs into a uniform two-dimensional bi-layered superstructure. This self-assembly process can be controlled by the energy of ligand-ligand interactions between surface ligands on Fe3 O4 NCs and Zr6 O4 (OH)4 (fumarate)6 MOF NPs. Scanning transmission electron microscopy (TEM)/energy-dispersive X-ray spectroscopy and TEM tomography confirm the hierarchical co-assembly of Fe3 O4 NCs with MOF NPs as ligand energies are manipulated to promote facile diffusion of the smaller NCs. First-principles calculations and event-driven molecular dynamics simulations indicate that the observed patterns are dictated by combination of ligand-surface and ligand-ligand interactions. This study opens a new avenue for design and self-assembly of MOFs and NCs into high surface area assemblies, mimicking the structure of supported catalyst architectures, and provides a thorough fundamental understanding of the self-assembly process, which could be a guide for designing functional materials with desired structure.
Palavras-chave
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2018 Tipo de documento: Article País de afiliação: Estados Unidos
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2018 Tipo de documento: Article País de afiliação: Estados Unidos