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Online Biogenic Carbon Analysis Enables Refineries to Reduce Carbon Footprint during Coprocessing Biomass- and Petroleum-Derived Liquids.
Dell'Orco, Stefano; Christensen, Earl D; Iisa, Kristiina; Starace, Anne K; Dutta, Abhijit; Talmadge, Michael S; Magrini, Kimberly A; Mukarakate, Calvin.
Afiliação
  • Dell'Orco S; Department of Industrial Engineering, University of Florence, Viale Morgagni 40, 50135 Florence, Italy.
  • Christensen ED; Catalytic Carbon Transformation and Scale-up Center, National Renewable Energy Laboratory, 15523 Denver West Parkway, Golden, Colorado 80401-3393, United States.
  • Iisa K; Catalytic Carbon Transformation and Scale-up Center, National Renewable Energy Laboratory, 15523 Denver West Parkway, Golden, Colorado 80401-3393, United States.
  • Starace AK; Catalytic Carbon Transformation and Scale-up Center, National Renewable Energy Laboratory, 15523 Denver West Parkway, Golden, Colorado 80401-3393, United States.
  • Dutta A; Catalytic Carbon Transformation and Scale-up Center, National Renewable Energy Laboratory, 15523 Denver West Parkway, Golden, Colorado 80401-3393, United States.
  • Talmadge MS; Catalytic Carbon Transformation and Scale-up Center, National Renewable Energy Laboratory, 15523 Denver West Parkway, Golden, Colorado 80401-3393, United States.
  • Magrini KA; Catalytic Carbon Transformation and Scale-up Center, National Renewable Energy Laboratory, 15523 Denver West Parkway, Golden, Colorado 80401-3393, United States.
  • Mukarakate C; Catalytic Carbon Transformation and Scale-up Center, National Renewable Energy Laboratory, 15523 Denver West Parkway, Golden, Colorado 80401-3393, United States.
Anal Chem ; 93(10): 4351-4360, 2021 03 16.
Article em En | MEDLINE | ID: mdl-33645225
To mitigate green-house gas (GHG) emissions, governments around the world are enacting legislation to reduce carbon intensity in transportation fuels. Coprocessing biomass and petroleum-derived liquids in existing refineries is a near-term, cost-effective approach for introducing renewable carbon in fuels and enabling refineries to meet regulatory mandates. However, coprocessing biomass-derived liquids in refineries results in variable degrees of biogenic carbon incorporation, necessitating accurate quantification to verify compliance with mandates. Existing refinery control and instrumentation systems lack the means to measure renewable carbon accurately, reliably, and quickly. Thus, accurate measurement of biogenic carbon is key to ensuring refineries meet regulatory mandates. In this Perspective, we present existing methods for measuring biogenic carbon, point out their challenges, and discuss the need for new online analytical capabilities to measure biogenic carbon in fuel intermediates.
Assuntos

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Petróleo Idioma: En Revista: Anal Chem Ano de publicação: 2021 Tipo de documento: Article País de afiliação: Itália

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Petróleo Idioma: En Revista: Anal Chem Ano de publicação: 2021 Tipo de documento: Article País de afiliação: Itália