Reactivity of [Pt(P t Bu3)2] with Zinc(I/II) Compounds: Bimetallic Adducts, Zn-Zn Bond Cleavage, and Cooperative Reactivity.
Organometallics
; 40(8): 1113-1119, 2021 Apr 26.
Article
em En
| MEDLINE
| ID: mdl-34602699
ABSTRACT
Metal-only Lewis pairs (MOLPs) based on zinc electrophiles are particularly interesting due to their relevance to Negishi cross-coupling reactions. Zinc-based ligands in bimetallic complexes also render unique reactivity to the transition metals at which they are bound. Here we explore the use of sterically hindered [Pt(P t Bu3)2] (1) to access Pt/Zn bimetallic complexes. Compounds [(P t Bu3)2Pt â Zn(C6F5)2] (2) and [Pt(ZnCp*)6] (3) (Cp* = pentamethylcyclopentadienyl) were isolated by reactions with Zn(C6F5)2 and [Zn2Cp*2], respectively. We also disclose the cooperative reactivity of 1/ZnX2 pairs (X = Cl, Br, I, and OTf) toward water and dihydrogen, which can be understood in terms of bimetallic frustration.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Organometallics
Ano de publicação:
2021
Tipo de documento:
Article
País de afiliação:
Espanha