Synthesis and Evaluation of LaBaCo2-xMoxO5+δ Cathode for Intermediate-Temperature Solid Oxide Fuel Cells.
Materials (Basel)
; 15(17)2022 Aug 25.
Article
em En
| MEDLINE
| ID: mdl-36079242
ABSTRACT
LaBaCo2-xMoxO5+δ (LBCMx, x = 0-0.08) cathodes synthesized by a sol-gel method were evaluated for intermediate-temperature solid oxide fuel cells. The limit of the solid solubility of Mo in LBCMx was lower than 0.08. As the content of Mo increased gradually from 0 to 0.06, the thermal expansion coefficient decreased from 20.87 × 10-6 K-1 to 18.47 × 10-6 K-1. The introduction of Mo could increase the conductivity of LBCMx, which varied from 464 S cm-1 to 621 S cm-1 at 800 °C. The polarization resistance of the optimal cathode LBCM0.04 in air at 800 °C was 0.036 Ω cm2, reduced by a factor of 1.67 when compared with the undoped Mo cathode. The corresponding maximum power density of a single cell based on a YSZ electrolyte improved from 165 mW cm-2 to 248 mW cm-2 at 800 °C.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Materials (Basel)
Ano de publicação:
2022
Tipo de documento:
Article
País de afiliação:
China