Pinecone biochar for the Adsorption of chromium (VI) from wastewater: Kinetics, thermodynamics, and adsorbent regeneration.

ABSTRACT

High concentration of chromium in aquatic environments is the trigger for researchers to remediate it from wastewater environments. However, conventional water treatment methods have not been satisfactory in removing chromium from water and wastewater over the last decade. Similarly, many adsorption studies have been focused on one aspect of the treatment, but this study dealt with all aspects of adsorption packages to come up with a concrete conclusion. Therefore, this study aimed to prepare pinecone biochar (PBC) via pyrolysis and apply it for Cr(VI) removal from wastewater. The PBC was characterized using FTIR, SEM-EDX, BET surface area, pHpzc, Raman analyses, TGA, and XRD techniques. Chromium adsorption was studied under the influence of PBC dose, solution pH, initial Cr(VI) concentration, and contact time. The characteristics of PBC are illustrated by FTIR spectroscopic functional groups, XRD non-crystallite structure, SEM rough surface morphology, and high BET surface area125 m2/g, pore volume, 0.07 cm3/g, and pore size 1.4 nm. On the other hand, the maximum Cr (VI) adsorption of 69% was found at the experimental condition of pH 2, adsorbent dosage 0.25 mg/50 mL, initial Cr concentration 100 mg/L, and contact time of 120 min. Similarly, the experimental data were well-fitted with the Langmuir adsorption isotherm at R2 0.96 and the pseudo-second-order kinetics model at R2 0.99. This implies the adsorption process is mainly attributed to monolayer orientation between the adsorbent and adsorbate. In the thermodynamics study of adsorption, ΔG was found to be negative implying the adsorption process was feasible and spontaneous whereas the positive values of ΔH and ΔS indicated the adsorption process was endothermic and increasing the degree of randomness, respectively. Finally, adsorbent regeneration and reusability were successful up to three cycles. In conclusion, biochar surface modification and reusability improvements are urgently required before being applied at the pilot scale.