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Mass-selective instability and resonance ejection modes for DIT with rectangular asymmetric wave shape.
Ivanov, A I; Sysoev, A A; Konenkov, N V.
Afiliação
  • Ivanov AI; Laboratory of Quadrupole Mass Spectrometry, Ryazan State University named after S.A. Yesenin, Ryazan, Russia.
  • Sysoev AA; Laboratory of Applied Ion Physics and Mass Spectrometry, National Research Nuclear University MEPhI (Moscow Engineering Physics Institute), Moscow, Russia.
  • Konenkov NV; Laboratory of Quadrupole Mass Spectrometry, Ryazan State University named after S.A. Yesenin, Ryazan, Russia.
Eur J Mass Spectrom (Chichester) ; : 14690667241270234, 2024 Aug 07.
Article em En | MEDLINE | ID: mdl-39109583
ABSTRACT
We consider the operation of a digital linear ion trap with resonance radial ejection and mass selective instability modes. Periodic wave shape has a positive part with amplitude V+=V0 and duration 0.8T and negative part with amplitude V-=-4V0 and duration 0.2T, where T is the period. The mapping of the stability diagram, calculations of the well's depth and ion oscillations spectra are presented. The process of resonant excitation of ion oscillations by a dipole sinusoidal signal is studied, as well as ion ejection at the stability boundary. The trajectory method is used for this purpose. It is shown that the mass selectivity of dipole excitation is twice as large for rectangular wave shape compared to sinusoidal wave shape. Increasing the diameter of the round rods of the linear trap gives an increase in the resolving power. The possibility of DIT operation in mass-selective instability mode at the boundary point qb=0.39 is discussed.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Eur J Mass Spectrom (Chichester) Ano de publicação: 2024 Tipo de documento: Article País de afiliação: Federação Russa

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Eur J Mass Spectrom (Chichester) Ano de publicação: 2024 Tipo de documento: Article País de afiliação: Federação Russa