Mass-selective instability and resonance ejection modes for DIT with rectangular asymmetric wave shape.
Eur J Mass Spectrom (Chichester)
; : 14690667241270234, 2024 Aug 07.
Article
em En
| MEDLINE
| ID: mdl-39109583
ABSTRACT
We consider the operation of a digital linear ion trap with resonance radial ejection and mass selective instability modes. Periodic wave shape has a positive part with amplitude V+=V0 and duration 0.8T and negative part with amplitude V-=-4V0 and duration 0.2T, where T is the period. The mapping of the stability diagram, calculations of the well's depth and ion oscillations spectra are presented. The process of resonant excitation of ion oscillations by a dipole sinusoidal signal is studied, as well as ion ejection at the stability boundary. The trajectory method is used for this purpose. It is shown that the mass selectivity of dipole excitation is twice as large for rectangular wave shape compared to sinusoidal wave shape. Increasing the diameter of the round rods of the linear trap gives an increase in the resolving power. The possibility of DIT operation in mass-selective instability mode at the boundary point qb=0.39 is discussed.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Eur J Mass Spectrom (Chichester)
Ano de publicação:
2024
Tipo de documento:
Article
País de afiliação:
Federação Russa