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1.
PLoS One ; 19(3): e0295381, 2024.
Artigo em Inglês | MEDLINE | ID: mdl-38466676

RESUMO

The objective is to investigate the healing efficacy of a Chromolaena odorata layered-nitrile rubber transdermal patch on excision wound healing in rats. Wounds were induced in Sprague-Dawley rats and were later treated as follows: wound A, the negative control, received no treatment (NC); wound B, the negative control with an empty nitrile rubber patch (NC-ERP); wound C, treated with a C. odorata layered-nitrile rubber patch (CO-NRP); and wound D, the positive control with Solcoseryl gel with a nitrile rubber patch (PC-SG-NRP). After 1, 3, 6, 10, and 14 days, the rats were sacrificed and analyzed for wound contraction, protein content, hexosamine, and uronic acid levels. Macroscopic observation showed enhanced wound healing in wounds treated with CO-NRP with a wound contraction percentage significantly higher (p<0.05) on days 6 and 10 compared to those treated with NC-ERP. Similarly, protein, hexosamine, and uronic acid contents were also significantly higher (p<0.05) in CO-NRP-treated wounds when compared with wounds treated with NC-ERP. Histological findings showed denser collagen deposition and faster granulation tissue formation in wounds treated with CO-NRP. From the results obtained, it is concluded that the C. odorata layered-nitrile rubber transdermal patch was effective in healing skin wounds.


Assuntos
Chromolaena , Borracha , Ratos , Animais , Borracha/metabolismo , Polímeros/metabolismo , Adesivo Transdérmico , Ratos Sprague-Dawley , Extratos Vegetais/farmacologia , Cicatrização , Pele/metabolismo , Colágeno/metabolismo , Ácidos Urônicos , Hexosaminas
2.
Zootaxa ; 5418(5): 551-575, 2024 Mar 04.
Artigo em Inglês | MEDLINE | ID: mdl-38480341

RESUMO

Four new species of trachelid spiders belonging to the genus Utivarachna Kishida, 1940 are described: U. angsoduo sp. nov., U. balonku sp. nov., U. rimba sp. nov., and U. trisula sp. nov. Part of the EFForTS project, the spider specimens were uncovered in a canopy fogging collection of tree crown arthropods along a land-use gradient from rainforest via jungle rubber (rubber agroforestry) to monocultures of rubber and oil palm in Jambi Province, Sumatra, Indonesia. Three of the proposed new species were found exclusively in rainforest or jungle rubber agroforest (U. angsoduo sp. nov., U. rimba sp. nov., U. trisula sp. nov.), and one of them exclusively in monocultures of rubber trees (U. balonku sp. nov.). We provide photographs and distribution maps for the proposed new species, and discuss their potential ecology based on their sampling locations. We also encountered a fifth species of the genus in all four land-use systems, U. phyllicola Deeleman-Reinhold, 2001, one of two species of the genus previously recorded from Sumatra, and also provide photographs and distribution maps for this species in the research area of the EFForTS project.


Assuntos
Borracha , Aranhas , Animais , Indonésia , Floresta Úmida , Distribuição Animal
3.
Environ Monit Assess ; 196(4): 356, 2024 Mar 11.
Artigo em Inglês | MEDLINE | ID: mdl-38467961

RESUMO

This study investigates the major environmental and socio-economic impacts of an increase in the area of rubber plantations and the changing patterns of drivers of land use changes. Using a combination of geospatial techniques and socio-economic methods, we mainly analyzed the rate of increase in area under rubber plantations, the major impacts of land use changes, and the changing drivers of land use changes. Our results show that the area under rubber plantations has increased significantly within the study area, with the area under rubber plantations increasing from 30 to 74% of the total area within five decades. Impact assessment of land use changes based on household surveys showed significant improvement in the socio-economic conditions of the farmers, however, at the expense of severe environmental degradation. Our results also indicate that while areas under rubber plantations continue to increase, the drivers of land use changes have changed over time. Furthermore, it has been observed that in the past, many interventions prioritized social and economic development and placed less emphasis on the ecological stability of the region. Perceptions of farmers revealed that the effects of ecological fragility already affected the economic robustness of the whole area. Therefore, we conclude that government interventions to support additional rubber cultivation should also focus on ecosystem stabilization in order to minimize the risk of an ecological catastrophe that would significantly affect the economic prosperity of the region.


Assuntos
Ecossistema , Borracha , Agricultura , Monitoramento Ambiental , Índia , Conservação dos Recursos Naturais
4.
Int J Mol Sci ; 25(5)2024 Mar 02.
Artigo em Inglês | MEDLINE | ID: mdl-38474173

RESUMO

Transgenic technology is a crucial tool for gene functional analysis and targeted genetic modification in the para rubber tree (Hevea brasiliensis). However, low efficiency of plant regeneration via somatic embryogenesis remains a bottleneck of successful genetic transformation in H. brasiliensis. Enhancing expression of GROWTH-REGULATING FACTOR 4 (GRF4)-GRF-INTERACTING FACTOR 1 (GIF1) has been reported to significantly improve shoot and embryo regeneration in multiple crops. Here, we identified endogenous HbGRF4 and HbGIF1 from the rubber clone Reyan7-33-97, the expressions of which dramatically increased along with somatic embryo (SE) production. Intriguingly, overexpression of HbGRF4 or HbGRF4-HbGIF1 markedly enhanced the efficiency of embryogenesis in two H. brasiliensis callus lines with contrasting rates of SE production. Transcriptional profiling revealed that the genes involved in jasmonic acid response were up-regulated, whereas those in ethylene biosynthesis and response as well as the S-adenosylmethionine-dependent methyltransferase activity were down-regulated in HbGRF4- and HbGRF4-HbGIF1-overexpressing H. brasiliensis embryos. These findings open up a new avenue for improving SE production in rubber tree, and help to unravel the underlying mechanisms of HbGRF4-enhanced somatic embryogenesis.


Assuntos
Hevea , Hevea/genética , Borracha/metabolismo , Látex , Regulação da Expressão Gênica de Plantas
5.
Sci Total Environ ; 922: 171393, 2024 Apr 20.
Artigo em Inglês | MEDLINE | ID: mdl-38431175

RESUMO

N,N'-substituted p-phenylenediamines (PPDs) are widely used antioxidants in rubber tires, which could be released and accumulated in road dusts with rubber tires wear. As ozonation product of N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine (6PPD), 6PPD-quinone (6PPD-Q) exhibited higher toxicity to coho salmon. However, studies on their environmental behaviors are still limited. Road dust is the major medium PPDs exist, which significantly affects the levels of PPDs in other mediums, especially surface water and particulate matter. In this study, road dust samples were collected in 55 major cities of China to explore the distribution characteristics of PPDs and 6PPD-Q. The concentrations of total PPDs (ΣPPDs) and 6PPD-Q in urban trunk road dust samples were in the ranges of 7.90-727 and 3.00-349 ng/g, with median concentrations of 68 and 49 ng/g, respectively. 6PPD and 6PPD-Q are the dominant components in most road dusts. The functional region-dependent pollution characteristics of PPDs and 6PPD-Q give the first finding that urban tunnel road was the highly polluted region, followed by urban trunk roads. Suburban road dusts had a lower pollution level. Moreover, the estimated daily intake (EDI) of PPDs and 6PPD-Q for children was much higher than adults.


Assuntos
Monitoramento Ambiental , Borracha , Adulto , Criança , Humanos , Antioxidantes , Poeira/análise , Quinonas
6.
PLoS One ; 19(3): e0297284, 2024.
Artigo em Inglês | MEDLINE | ID: mdl-38512907

RESUMO

Addressing the profound impact of Tapping Panel Dryness (TPD) on yield and quality in the global rubber industry, this study introduces a cutting-edge Otsu threshold segmentation technique, enhanced by Dung Beetle Optimization (DBO-Otsu). This innovative approach optimizes the segmentation threshold combination by accelerating convergence and diversifying search methodologies. Following initial segmentation, TPD severity levels are meticulously assessed using morphological characteristics, enabling precise determination of optimal thresholds for final segmentation. The efficacy of DBO-Otsu is rigorously evaluated against mainstream benchmarks like Peak Signal-to-Noise Ratio (PSNR), Structural Similarity Index (SSIM), and Feature Similarity Index (FSIM), and compared with six contemporary swarm intelligence algorithms. The findings reveal that DBO-Otsu substantially surpasses its counterparts in image segmentation quality and processing speed. Further empirical analysis on a dataset comprising TPD cases from level 1 to 5 underscores the algorithm's practical utility, achieving an impressive 80% accuracy in severity level identification and underscoring its potential for TPD image segmentation and recognition tasks.


Assuntos
Hevea , Borracha , Algoritmos , Processamento de Imagem Assistida por Computador/métodos
7.
PLoS One ; 19(2): e0286672, 2024.
Artigo em Inglês | MEDLINE | ID: mdl-38408064

RESUMO

This ex vivo study aimed to investigate surface roughness and substance loss after treatment with different professional cleaning methods and to determine whether subsequent polishing with a rubber cup and polishing paste is necessary. Samples (flat and natural surfaces) of human enamel and dentin were prepared (baseline) and treated with either a curette, air-polishing with erythritol, a rubber cup and polishing paste, or a combination thereof (treatment). Subsequently, all samples were immersed in an ultrasonic bath (ultrasonic) to remove residues from the treatment procedures. The surface roughness values sRa and sRz as well as tissue loss were measured profilometrically. Linear regression models were used to compare group differences (roughness and loss) considering the corresponding baseline value. The significance level was set at p<0.05. sRa increased significantly after treatment with curettes or air-polishing with erythritol in both enamel (p<0.001) and dentin (p<0.001) of flat samples. The same effect was observed for sRz in dentin (p<0.001) but not for enamel compared to negative control. Polishing with a rubber cup and paste alone had no significant effect on roughness values. When combined with other treatments, the effect of curette or air-polishing with erythritol dominated the effect. In enamel, none of the tested methods led to measurable tissue loss. In dentin, air-polishing with erythritol caused ≤50% tissue loss compared to the curette. Conclusively, for enamel, treatment effects on roughness were measurable but of limited clinical relevance. For dentin, air-polishing resulted in a smaller but insignificant roughness increase and less tissue loss compared to the curette. Polishing with a rubber cup and paste did not affect surface roughness. Regarding the clinical application, the use of air-polishing seems to be a less invasive procedure than using a curette; polishing with rubber cup and paste offers no advantage in terms of reducing roughness as a final procedure.


Assuntos
Eritritol , Borracha , Humanos , Propriedades de Superfície , Polimento Dentário
9.
Gene ; 908: 148278, 2024 May 25.
Artigo em Inglês | MEDLINE | ID: mdl-38360121

RESUMO

Eucommia ulmoides (E. ulmoides) is widely cultivated and exhibits remarkable adaptability in China. It is the most promising rubber source plant in the temperate zone. E. ulmoides gum (EUG) is a trans-polyisoprene with a unique "rubber-plastic duality", and is widely used in advanced materials and biomedical fields. The transcription of Farnesyl pyrophosphate synthase (FPS), the rate-limiting enzyme of EUG biosynthesis, is controlled by regulatory mechanisms that remain poorly elucidated. In this research, 12 TGA transcription factors (TFs) in E. ulmoides were identified. Promoter prediction results revealed that the EuFPS1 promoter had binding sites for EuTGAs. Subsequently, the EuTGA1 was obtained by screening the E. ulmoides cDNA library using the EuFPS1 promoter as a bait. The individual yeast one­hybrid and dual-luciferase assays confirmed that in the tobacco plant, EuTGA1 interacted with the EuFPS1 promoter, resulting in a more than threefold increase in the activity of the EuFPS1. Subcellular localization study further revealed that EuTGA1 is localized in the nucleus and acts as a TF to regulate EuFPS1 expression. In addition, qRT-PCR analysis demonstrated that the expression trend of EuFPS1 and EuTGA1 was the same at different time of the year. Notably, low temperature and MeJA treatments down-regulated EuTGA1 expression. Additionally, the transient transformation of EuTGA1 enhanced NtFPS1 expression in tobacco plants. Overall, this study identified a TF that interacted with EuFPS1 promoter to positively regulate EuFPS1 expression. The findings of this study provide a theoretical basis for further research on the expression regulation of EuFPS1.


Assuntos
Eucommiaceae , Borracha , Borracha/metabolismo , Eucommiaceae/genética , Eucommiaceae/química , Eucommiaceae/metabolismo , Fatores de Transcrição de Zíper de Leucina Básica/genética , Biblioteca Gênica , Geraniltranstransferase/genética
10.
Ecotoxicol Environ Saf ; 273: 116134, 2024 Mar 15.
Artigo em Inglês | MEDLINE | ID: mdl-38387143

RESUMO

The leaching of additives from plastics and elastomers (rubbers) has raised concerns due to their potential negative impacts on the environment and the development of antibiotic resistance. In this study, we investigated the effects of chemicals extracted from two types of rubber on microbiomes derived from a benthic sea urchin and two pelagic fish species. Additionally, we examined whether bacterial communities preconditioned with rubber-associated chemicals displayed adaptations to antibiotics. At the highest tested concentrations of chemicals, we observed reduced maximum growth rates and yields, prolonged lag phases, and increased alpha diversity. While the effects on alpha and beta diversity were not always conclusive, several bacterial genera were significantly influenced by chemicals from the two rubber sources. Subsequent exposure of sea urchin microbiomes preconditioned with rubber chemicals to the antibiotic ciprofloxacin resulted in decreased maximum growth rates. This indicates a more sensitive microbiome to ciprofloxacin when preconditioned with rubber chemicals. Although no significant interaction effects between rubber chemicals and ciprofloxacin exposure were observed in bacterial alpha and beta diversity, we observed log-fold changes in two bacterial genera in response to ciprofloxacin exposure. These findings highlight the structural and functional alterations in microbiomes originating from various marine species when exposed to rubber-associated chemicals and underscore the potential risks posed to marine life.


Assuntos
Microbiota , Borracha , Animais , Antibacterianos/toxicidade , Plásticos , Ciprofloxacina/toxicidade
11.
Sci Rep ; 14(1): 4283, 2024 02 21.
Artigo em Inglês | MEDLINE | ID: mdl-38383610

RESUMO

The Russian dandelion (Taraxacum koksaghyz) grows in temperate zones and produces large amounts of poly(cis-1,4-isoprene) in its roots, making it an attractive alternative source of natural rubber. Most T. koksaghyz plants require vernalization to trigger flower development, whereas early flowering varieties that have lost their vernalization dependence are more suitable for breeding and domestication. To provide insight into the regulation of flowering time in T. koksaghyz, we induced epigenetic variation by in vitro cultivation and applied epigenomic and transcriptomic analysis to the resulting early flowering plants and late flowering controls, allowing us to identify differences in methylation patterns and gene expression that correlated with flowering. This led to the identification of candidate genes homologous to vernalization and photoperiodism response genes in other plants, as well as epigenetic modifications that may contribute to the control of flower development. Some of the candidate genes were homologous to known floral regulators, including those that directly or indirectly regulate the major flowering control gene FT. Our atlas of genes can be used as a starting point to investigate mechanisms that control flowering time in T. koksaghyz in greater detail and to develop new breeding varieties that are more suited to domestication.


Assuntos
Magnoliopsida , Taraxacum , Borracha/metabolismo , Taraxacum/genética , Taraxacum/metabolismo , Magnoliopsida/metabolismo , Epigenômica , Regulação da Expressão Gênica de Plantas , Melhoramento Vegetal , Epigênese Genética , Federação Russa , Flores/fisiologia
12.
Plant Sci ; 341: 112011, 2024 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-38311252

RESUMO

Currently, one of the most serious threats to rubber tree is the tapping panel dryness (TPD) that greatly restricts natural rubber production. Over-tapping or excessive ethephon stimulation is regarded as the main cause of TPD occurrence. Although extensive studies have been carried out, the molecular mechanism underlying TPD remains puzzled. An attempt was made to compare the levels of endogenous hormones and the profiles of transcriptome and proteome between healthy and TPD trees. Results showed that most of endogenous hormones such as jasmonic acid (JA), 1-aminocyclopropanecarboxylic acid (ACC), indole-3-acetic acid (IAA), trans-zeatin (tZ) and salicylic acid (SA) in the barks were significantly altered in TPD-affected rubber trees. Accordingly, multiple hormone-mediated signaling pathways were changed. In total, 731 differentially expressed genes (DEGs) and 671 differentially expressed proteins (DEPs) were identified, of which 80 DEGs were identified as putative transcription factors (TFs). Further analysis revealed that 12 DEGs and five DEPs regulated plant hormone synthesis, and that 16 DEGs and six DEPs were involved in plant hormone signal transduction pathway. Nine DEGs and four DEPs participated in rubber biosynthesis and most DEGs and all the four DEPs were repressed in TPD trees. All these results highlight the potential roles of endogenous hormones, signaling pathways mediated by these hormones and rubber biosynthesis pathway in the defense response of rubber trees to TPD. The present study extends our understanding of the nature and mechanism underlying TPD and provides some candidate genes and proteins related to TPD for further research in the future.


Assuntos
Hevea , Hevea/genética , Hevea/metabolismo , Borracha/metabolismo , Transcriptoma , Látex/metabolismo , Proteoma/metabolismo , Reguladores de Crescimento de Plantas/metabolismo , Proteínas de Plantas/genética , Proteínas de Plantas/metabolismo , Transdução de Sinais , Hormônios/metabolismo , Regulação da Expressão Gênica de Plantas
13.
ACS Appl Mater Interfaces ; 16(7): 9506-9516, 2024 Feb 21.
Artigo em Inglês | MEDLINE | ID: mdl-38346320

RESUMO

In a world increasingly driven by data, wearable triboelectric nanogenerators (TENGs) offer a convenient way to monitor and collect information about human body motions. To meet the demands of the large-scale production of wearable TENGs, material selection to realize a high conversion efficiency and simplify the fabrication process remains a challenge. To address these issues, we present a simple-structured wearable printed arc-shaped triboelectric sensor (PATS) for finger motion detection by leveraging inkjet printing technology. In this regard, pressure sensors composed of diverse materials based on dielectric-dielectric and metal-dielectric structures in contact-separation mode were fabricated and compared. Thanks to the unique characteristics of the silver nanoparticle (Ag-NP)-printed layer and silicon rubber (SR), the SR-Ag PATS shows a high peak-to-peak voltage of 14.15 V and a short-circuit current of 0.78 µA. The proposed sensor with the capability of accurately identifying finger motions at various bending angles suggests promising application potential in glove-based human-machine interface (HMI) systems.


Assuntos
Nanopartículas Metálicas , Dispositivos Eletrônicos Vestíveis , Humanos , Prata , Dedos , Movimento (Física) , Borracha , Silício
14.
J Environ Manage ; 353: 120122, 2024 Feb 27.
Artigo em Inglês | MEDLINE | ID: mdl-38308983

RESUMO

This review deals with waste rubber recycling by devulcanization treatment using microwave method. In fact, vulcanized rubbers have been extensively used in various fields due to their superior performances. Subsequently, the massive use of such materials, especially in the automotive industry, has generated a substantial amount of wastes which are not easily to be degraded due to the three-dimensional network formed by the vulcanization process. One of the optimal solutions for the successful recycling of rubber is devulcanization, i.e., the process in which the sulfur bonds in the vulcanized material are selectively broken. Currently, to achieve rubber devulcanization, the microwave treatment has been proposed as a promising alternative process due to its precise manipulation of process variables. Furthermore, the microwave process is easily to be coupled with effects of other elements such as chemical and swelling agents. In this work, different microwave devulcanization methods are reviewed, the utilization of the corresponding devulcanized materials has also been discussed. The reviewed contents are believed to be of great interest to academics and industries since they represent a great challenge from scientific, economic and environmental points of view.


Assuntos
Micro-Ondas , Borracha , Borracha/química , Borracha/metabolismo , Reciclagem/métodos
15.
Environ Pollut ; 346: 123670, 2024 Apr 01.
Artigo em Inglês | MEDLINE | ID: mdl-38423271

RESUMO

Drivers commonly navigate their vehicles at moderate speeds in proximity to traffic lights. In this study, road dust samples were collected in the vicinity of traffic lights, as well as at a taxi stand (TS) situated between traffic lights, with considerations given to both forward direction (FD) and backward direction (BD). The characterization of tire wear particles (TWPs) in the road dust was meticulously conducted based on particle size. Notably, tire-road wear particles (TRWPs) were conspicuously absent in samples surpassing 500 µm. Furthermore, TRWPs comprised less than 1% of identified particles in the road dust samples of 212-500 µm, with their origin traceable to heavy vehicles rather than passenger cars. The abundance of TRWPs from heavy vehicles exhibited marked variations, with heightened prevalence in the TS and BD samples as opposed to the FD sample. For the samples smaller than 212 µm, the composition of natural rubber (NR) in TWPs demonstrated a diminishing trend with escalating particle size. Conversely, the composition of styrene-butadiene rubber (SBR) exhibited an upward trajectory independent of the sampling site. The NR composition ratio in TWPs followed the order: TS (17-55%) > FD (17-47%) > BD (13-36%), while the SBR composition ratio exhibited the sequence: BD (62-86%) > FD (48-79%) > TS (24-70%). The TWP concentrations in road dust obtained from the TS (0.35-0.82%) were discernibly lower than those in the FD (0.54-1.77%) and BD (0.61-1.29%) samples. Specifically, the average TWP concentrations in road dust samples, falling within the size range of 20-212 µm, were 0.45%, 1.06%, and 0.91% for the TS, FD, and BD samples, respectively. These concentrations were lower than the corresponding values observed in samples collected from a bus stop.


Assuntos
Poeira , Emissões de Veículos , Poeira/análise , Emissões de Veículos/análise , Monitoramento Ambiental , Tamanho da Partícula , Automóveis , Borracha
16.
Nature ; 627(8002): 116-122, 2024 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-38355803

RESUMO

Terrestrial animal biodiversity is increasingly being lost because of land-use change1,2. However, functional and energetic consequences aboveground and belowground and across trophic levels in megadiverse tropical ecosystems remain largely unknown. To fill this gap, we assessed changes in energy fluxes across 'green' aboveground (canopy arthropods and birds) and 'brown' belowground (soil arthropods and earthworms) animal food webs in tropical rainforests and plantations in Sumatra, Indonesia. Our results showed that most of the energy in rainforests is channelled to the belowground animal food web. Oil palm and rubber plantations had similar or, in the case of rubber agroforest, higher total animal energy fluxes compared to rainforest but the key energetic nodes were distinctly different: in rainforest more than 90% of the total animal energy flux was channelled by arthropods in soil and canopy, whereas in plantations more than 50% of the energy was allocated to annelids (earthworms). Land-use change led to a consistent decline in multitrophic energy flux aboveground, whereas belowground food webs responded with reduced energy flux to higher trophic levels, down to -90%, and with shifts from slow (fungal) to fast (bacterial) energy channels and from faeces production towards consumption of soil organic matter. This coincides with previously reported soil carbon stock depletion3. Here we show that well-documented animal biodiversity declines with tropical land-use change4-6 are associated with vast energetic and functional restructuring in food webs across aboveground and belowground ecosystem compartments.


Assuntos
Biodiversidade , Metabolismo Energético , Cadeia Alimentar , Floresta Úmida , Animais , Artrópodes/metabolismo , Bactérias/metabolismo , Aves/metabolismo , Sequestro de Carbono , Fezes , Fungos/metabolismo , Indonésia , Oligoquetos/metabolismo , Compostos Orgânicos/metabolismo , Óleo de Palmeira , Borracha , Solo/química , Clima Tropical
17.
Int J Biol Macromol ; 262(Pt 1): 129980, 2024 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-38340932

RESUMO

The present study investigates the biopolymer packaging film developed from carboxymethyl cellulose (CMC) with varying concentrations of natural rubber latex (NR) and oxidised natural rubber latex (ONR) using the solvent casting method. The physicochemical properties of the CMC/NR and CMC/ONR film samples were characterised using FTIR, TG/DTA, DSC, SEM, and XRD analysis. The increased concentration of NR and ONR helped to enhance mechanical characteristics, superior UV resistance, enhanced resistance to oxygen and water vapour penetration, improved dimensional stability, and a reduction in the moisture retention ability of the film samples. The CMC sample film, incorporated with 1.5 g ONR, was found to have more than a 100 % increase in the tensile strength. The tensile value increased from 21.56 MPa to 48.36 MPa, with the highest young modulus of 0.73 GPa and elastic stability of 7.14 %. The incorporation of NR and ONR significantly reduced the super water absorbency nature of the CMC film, and the moisture content values reduced from 21.6 % to ≅ 0.15 % for ONR-incorporated film. Additionally, the CMC/NR and CMC/ONR films exhibited high optical transparency values and were found to be fast biodegradable, substantiating their potential use in various packaging applications. Application of these materials in perishable fruit packaging has shown significant enhancement in shelf life, highlighting their practical efficiency and potential for sustainable packaging solutions.


Assuntos
Carboximetilcelulose Sódica , Borracha , Borracha/química , Carboximetilcelulose Sódica/química , Látex , Embalagem de Produtos , Embalagem de Medicamentos , Embalagem de Alimentos
18.
J Environ Manage ; 354: 120211, 2024 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-38340664

RESUMO

Peroxydisulfate (PDS) and peroxymonosulfate (PMS) could be efficiently activated by heat to generate reactive oxygen species (ROS) for the degradation of organic contaminants. However, defects including the inefficiency treatment and pH dependence of monooxidant process are prominent. In this study, synergy of heat and the PDS-PMS binary oxidant was studied for efficient triclosan (TCS) degradation and apply in rubber wastewater. Under different pH values, the degradation of TCS followed pseudo-first-order kinetics, the reaction rate constant (kobs) value of TCS in heat/PDS/PMS system increased from 1.8 to 4.4 fold and 6.8-49.1 fold when compared to heat/PDS system and heat/PMS system, respectively. Hydroxyl radicals (·OH), sulfate radicals (SO4·-) and singlet oxygen (1O2) were the major ROS for the degradation of TCS in heat/PDS/PMS system. In addition, the steady-state concentrations of ·OH/1O2 and SO4·-/·OH/1O2 increased under acidic conditions and alkaline conditions, respectively. It was concluded that the pH regulated the ROS for degradation of TCS in heat/PDS/PMS system significantly. Based on the analysis of degradation byproducts, it was inferred that the dechlorination, hydroxylation and ether bond breaking reactions occurred during the degradation of TCS. Moreover, the biological toxicity of the ten byproducts was lower than that of TCS was determined. Furthermore, the heat/PDS/PMS system is resistant to the influence of water substrates and can effectively improve the water quality of rubber wastewater. This study provides a novel perspective for efficient degradation of TCS independent of pH in the heat/PDS/PMS system and its application of rubber wastewater.


Assuntos
Triclosan , Poluentes Químicos da Água , Oxidantes/química , Águas Residuárias , Espécies Reativas de Oxigênio , Borracha , Oxirredução , Poluentes Químicos da Água/química , Peróxidos/química
19.
J Environ Manage ; 353: 120127, 2024 Feb 27.
Artigo em Inglês | MEDLINE | ID: mdl-38325281

RESUMO

The landscape in southwestern Ghana faces rampant modification due to socio-economic activities, posing threats to ecosystem service provision and environmental sustainability. Addressing these threats involves empowering land-use actors to design landscapes that offer multiple benefits concurrently. This study employs a geodesign framework, integrating participatory ecosystem service assessment and spatial simulations. This geodesign framework aims to design the landscape in a collaborative manner in a way that supports multiple benefits concurrently, mitigating the threats posed by landscape modification. Reflecting on local land-use perceptions during a workshop, we developed land-use options and land management strategies based on selected land-cover types. We identified urban greens, open space restoration, rubber mixed-stands, mangrove restoration, selective-cutting land preparation, soil conservation, and relay cropping as land-use options to target selected land-cover types of shrubland, cropland, smallholder rubber, smallholder palm, wetland, and settlement. The land management strategies translated into landscape scenarios based on local need conditions. We generated the local need conditions which translated into the landscape scenarios by reflecting on the location of land-cover types, 'change-effect' conditions within rubber, settlement, and cropland, and 'no-change'conditions within cropland. Results indicate synergies between the created landscape scenarios and ecosystem service provisioning, with 'no-change' within cropland providing the highest synergy and 'change-effect' within rubber providing the least synergy. Spatial modeling of local perceptions forms the novelty of this study, as the fusion of participatory assessments and spatial modeling allows for a more holistic understanding of the landscape, its services, and the potential implications of different management strategies. The geodesign framework facilitated the design of the complex heterogeneous landscape to visualize possibilities of maximizing multiple benefits and can be used for future planning on the landscape.


Assuntos
Ecossistema , Borracha , Gana , Conservação dos Recursos Naturais/métodos , Solo
20.
Appl Microbiol Biotechnol ; 108(1): 191, 2024 Feb 02.
Artigo em Inglês | MEDLINE | ID: mdl-38305904

RESUMO

Bacterial degradation of natural rubber (NR) in an oxic environment is initiated by oxidative cleavage of double bonds in the NR-carbon backbone and is catalyzed by extracellular haem-containing rubber oxygenases. NR-cleavage products of sufficiently low molecular mass are taken up by the cells and metabolized for energy and biomass formation. Gram-negative and Gram-positive NR-degrading bacteria (usually) employ different types of rubber oxygenases such as RoxA and/or RoxB (most Gram-negative NR-degraders) or latex clearing protein Lcp (most Gram-positive NR-degraders). In order to find novel orthologues of Rox proteins, we have revisited databases and provide an update of Rox-like proteins. We describe the putative evolution of rubber oxygenases and confirm the presence of a third subgroup of Rox-related proteins (RoxCs), the biological function of which remains, however, unclear. We summarize the knowledge on the taxonomic position of Steroidobacter cummioxidans 35Y and related species. Comparison of genomic and biochemical features of strain 35Y with other species of the genus Steroidobacter suggests that strain 35Y represents a species of a novel genus for which the designation Aurantibaculum gen. nov. is proposed. A short summary on the capabilities of NR-degrading consortia, that could be superior in biotechnological applications compared to pure cultures, is also provided. KEY POINTS: • Three types of rubber oxygenases exist predominantly in Gram-negative microbes • S. cummioxidans 35Y contains RoxA and RoxB which are superior in activity • S. cummioxidans 35Y represents a species of a novel genus.


Assuntos
Oxigenases , Borracha , Borracha/metabolismo , Oxigenases/metabolismo , Proteínas de Bactérias/metabolismo , Látex/metabolismo , Bactérias Gram-Negativas/genética , Bactérias Gram-Negativas/metabolismo
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