RESUMEN
The working principle of lateral flow assays, such as the widely used COVID-19 rapid tests, is based on the capillary-driven liquid transport of a sample fluid to a test line using porous polymeric membranes as the conductive medium. In order to predict this wicking process by simplified analytical models, it is essential to determine an effective capillary radius for the highly porous and open-pored membranes. In this work, a parametric study is performed with selected simplified structures, representing the complex microstructure of the membrane. For this, a phase-field approach with a special wetting boundary condition to describe the meniscus formation and the corresponding mean surface curvature for each structure setup is used. As a main result, an analytical correlation between geometric structure parameters and an effective capillary radius, based on a correction factor, are obtained. The resulting correlation is verified by applying image analysis methods on reconstructed computer tomography scans of two different porous polymeric membranes and thus determining the geometric structure parameters. Subsequently, a macroscale flow model that includes the correlated effective pore size and geometrical capillary radius is applied, and the results are compared with wicking experiments. Based on the derived correction function, it is shown that the analytical prediction of the wicking process in highly porous polymeric membranes is possible without the fitting of experimental wicking data. Furthermore, it can be seen that the estimated effective pore radius of the two membranes is 8 to 10 times higher than their geometric mean pore radii.
RESUMEN
Triply periodic minimal surface (TPMS) structures have a very good lightweight potential, due to their surface-to-volume ratio, and thus are contents of various applications and research areas, such as tissue engineering, crash structures, or heat exchangers. While TPMS structures with a uniform porosity or a linear gradient have been considered in the literature, this paper focuses on the investigation of the mechanical properties of gyroid structures with non-linear porosity gradients. For the realisation of the different porosity gradients, an algorithm is introduced that allows the porosity to be adjusted by definable functions. A parametric study is performed on the resulting gyroid structures by performing mechanical simulations in the linear deformation regime. The transformation into dimensionless parameters enables material-independent statements, which is possible due to linearity. Thus, the effective elastic behaviour depends only on the structure geometry. As a result, by introducing non-linear gradient functions and varying the density of the structure over the entire volume, specific strengths can be generated in certain areas of interest. A computational design of porosity enables an accelerated application-specific structure development in the field of engineering.
RESUMEN
Polymeric porous media (PPM) are widely used as advanced materials, such as sound dampening foams, lithium-ion batteries, stretchable sensors, and biofilters. The functionality, reliability, and durability of these materials have a strong dependence on the microstructural patterns of PPM. One underlying mechanism for the formation of porosity in PPM is phase separation, which engenders polymer-rich and polymer-poor (pore) phases. Herein, the phase separation in polymer solutions is discussed from two different aspects: diffusion and hydrodynamic effects. For phase separation governed by diffusion, two novel morphological transitions are reviewed: "cluster-to-percolation" and "percolation-to-droplets," which are attributed to an effect that the polymer-rich and the solvent-rich phases reach the equilibrium states asynchronously. In the case dictated by hydrodynamics, a deterministic nature for the microstructural evolution during phase separation is scrutinized. The deterministic nature is caused by an interfacial-tension-gradient (solutal Marangoni force), which can lead to directional movement of droplets as well as hydrodynamic instabilities during phase separation.
