Does microplastic really represent a threat? A review of the atmospheric contamination sources and potential impacts.

Microplastics (MPs) are regarded as one of the major atmospheric contaminants that have gained wide attention across the globe in the current dispensation. Airborne MPs have been collected in atmospheric fallouts, in indoor and outdoor air as well as along roadways and indoor dust. The most dominating constituent shapes and forms of identified airborne MPs are fibers and synthetic textiles, respectively. With the breathing mechanism as a spontaneous practice for survival, the inhalation of airborne MPs is an inevitable deal. The level of toxicity of MPs to organisms stems from its physiochemical speciation. The smaller size and almost weightless nature make it possible to suspend in the atmosphere and be inhaled and create potential health problems. Nonetheless, the data available concerning the presence of airborne MPs and its environmental and human health impacts is limited. In this review, we extensively discuss the rigorous and suitable methodologies adopted for the analysis of airborne MPs in previous studies. The characteristics and sources of airborne MPs, the potential health impacts on humans, and some mitigating measures have also been discussed thoroughly.

Effects of physicochemical properties of Au cyanidation tailings on cyanide microbial degradation.

The initial cyanide (CN-) concentration and amount of co-contaminants in GCTs can inhibit bacterial growth and reduce the CN--degrading ability of bacteria. Several microorganisms can biotransform a wide range of organic and inorganic industrial contaminants into nontoxic compounds. However, active enzymatic CN- metabolism processes are mostly constrained by the physical and chemical characteristics of GCTs. High concentrations of toxic metal co-contaminants, such as, Pb, and Cr, and factors, such as pH, temperature, and oxygen concentration create oxidative stress and limit the CN--degrading potential of cyanotrophic strains. The effects of such external and internal factors on the CN--degrading ability of bacteria hinder the selection of suitable microorganisms for CN- biodegradation. Therefore, understanding the effects of the physicochemical properties of GCTs on cyanobacteria strains can help identify suitable microbes and favorable environmental conditions to promote microbial growth and can also help design efficient CN- biodegradation processes. In this review, we present a detailed analysis of the physicochemical properties of GCTs and their effects on microbial CN- degradation.

Determination and detoxification of cyanide in gold mine tailings: A review.

Cyanide is among the most toxic chemicals widely employed in the cyanidation process to leach precious minerals, such as gold and silver, by the minerals processing companies worldwide. This present article reviews the determination and detoxification of cyanide found in gold mine tailings. Most of the cyanide remains in the solution or the slurries after the cyanidation process. The cyanide species in the gold tailings are classified as free cyanide, weak acid dissociation, and metallocyanide complexes. Several methods, such as colorimetric, titrimetric, and electrochemical, have been developed to determine cyanide concentrations in gold mine effluents. Application of physical, natural, biological, and chemical methods to detoxify cyanide to a permissible limit (50 mg L-1) can be achieved when the chemical compositions of cyanide (type of species) present in the tailings are known. The levels of cyanide concentration determine the impact it will have on the environment.