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1.
Sci Rep ; 14(1): 8526, 2024 04 12.
Article En | MEDLINE | ID: mdl-38609406

Understanding the efficacy of alternative phosphorus (P) sources in tropical soils is crucial for sustainable farming, addressing resource constraints, mitigating environmental impact, improving crop productivity, and optimizing soil-specific solutions. While the topic holds great importance, current literature falls short in providing thorough, region-specific studies on the effectiveness of alternative P sources in Brazilian tropical soils for maize cultivation. Our aim was to assess the agronomic efficiency of alternative P sources concerning maize crop (Zea mays L.) attributes, including height, shoot dry weight, stem diameter, and nutrient accumulation, across five Brazilian tropical soils. In greenhouse conditions, we carried out a randomized complete block design, investigating two factors (soil type and P sources), evaluating five tropical soils with varying clay contents and three alternative sources of P, as well as a commercial source and a control group. We evaluated maize crop attributes such as height, dry weight biomass, and nutrient accumulation, P availability and agronomic efficiency. Our results showed that, although triple superphosphate (TSP) exhibited greater values than alternative P sources (precipitated phosphorus 1, precipitated phosphorus 2 and reactive phosphate) for maize crop attributes (e.g., height, stem diameter, shoot dry weight and phosphorus, nitrogen, sulfur, calcium and magnesium accumulation). For instance, PP1 source increased nutrient accumulation for phosphorus (P), nitrogen (N), and sulfur (S) by 37.05% and 75.98% (P), 34.39% and 72.07% (N), and 41.94% and 72.69% (S) in comparison to PP2 and RP, respectively. Additionally, PP1 substantially increased P availability in soils with high clay contents 15 days after planting (DAP), showing increases of 61.90%, 99.04%, and 38.09% greater than PP2, RP, and TSP. For Ca and Mg accumulation, the highest values were found in the COxisol2 soil when PP2 was applied, Ca = 44.31% and 69.48%; and Mg = 46.23 and 75.79%, greater than PP1 and RP, respectively. Finally, the highest values for relative agronomic efficiency were observed in COxisol2 when PP1 was applied. The precipitated phosphate sources (PP1 and PP2) exhibited a similar behavior to that of the commercial source (TSP), suggesting their potential use to reduce reliance on TSP fertilization, especially in soils with low clay contents. This study emphasized strategies for soil P management, aimed at assisting farmers in enhancing maize crop productivity while simultaneously addressing the effectiveness of alternative P sources of reduced costs.


Phosphorus , Soil , Agriculture , Brazil , Clay , Nitrogen , Phosphates , Sulfur
2.
Environ Sci Pollut Res Int ; 26(32): 33582-33593, 2019 Nov.
Article En | MEDLINE | ID: mdl-31586315

High concentrations of heavy metals (HM) in soils have negative impacts on plants, human health, and the environmental quality. The purpose of this study was to evaluate the effects of biochars on the bioaccessibility of Zn, Pb, and Cd in a contaminated soil in the Tar Creek area of NE Oklahoma, as well as on the growth and uptake of these elements by perennial ryegrass (Lolium perenne). Biochars were produced from switchgrass (SGB) and poultry litter (PLB) feedstocks at 700 °C and applied to the soil at 0.0, 0.5, 1.0, 2.0, and 4.0% (w/w), with three replications. Regardless of the feedstock, both soil organic carbon (SOC or OC) and pH increased as the rates of biochars increased, which significantly decreased the HM bioaccessibility (p < 0.01). The Zn and Cd extracted by DTPA were highly correlated (p < 0.0001) with their concentration in ryegrass shoots and roots. Except for some significant positive correlations (p < 0.05), HM concentrations in ryegrass shoots and roots were not correlated with their biomass (p > 0.05). Both bioconcentration factor (BCF) and transfer factor decreased as the rates of biochars applied increased, especially for Pb and Cd (p < 0.01). Our results suggest it is beneficial to use biochars at Tar Creek as a soil amendment to reduce HM bioaccessibility and metal uptake by ryegrass.


Charcoal/chemistry , Metals, Heavy/analysis , Soil Pollutants/analysis , Biomass , Carbon , Environmental Pollution , Environmental Restoration and Remediation , Humans , Lolium , Oklahoma , Plant Roots/chemistry , Soil
3.
Sci Rep ; 8(1): 916, 2018 01 17.
Article En | MEDLINE | ID: mdl-29343823

The correct evaluation of silicon (Si) availability in different soil types is critical in defining the amount of Si to be supplied to crops. This study was carried out to evaluate two methods and five chemical Si extractants in clayey, sandy-loam, and sandy soils cultivated with sugarcane (Saccharum spp. hybrids). Soluble Si was extracted using two extraction methods (conventional and microwave oven) and five Si extractants (CaCl2, deionized water, KCl, Na-acetate buffer (pH 4.0), and acetic acid). No single method and/or extractant adequately estimated the Si availability in the soils. Conventional extraction with KCl was no more effective than other methods in evaluating Si availability; however, it had less variation in estimating soluble Si between soils with different textural classes. In the clayey and sandy soils, the Na-acetate buffer (pH 4.0) and acetic acid were effective in evaluating the Si availability in the soil regardless of the extraction methods. The extraction with acetic acid using the microwave oven, however, overestimated the Si availability. In the sandy-loam soil, extraction with deionized water using the microwave oven method was more effective in estimating the Si availability in the soil than the other extraction methods.

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