Occurrence, bioconcentration, and human health risks of pharmaceuticals in biota in the Sea of Marmara, Türkiye.

The presence, bioconcentration, and health risk via seafood consumption of 11 pharmaceutical compounds belonging to different therapeutic groups (anti-inflammatory, antiepileptic, lipid regulators, and hormones) were investigated in the muscle tissues of fish and the meat of shrimp in the Sea of Marmara. Six biota species (Merlangius merlangus, Trachurus meditterraneus, Serranus hepatus, Pomatomus saltatrix, Parapenaeus longirostris, Spratus sprattus) were collected from the five stations in October and April 2019. Ultrasonic extraction method followed by solid phase extraction was used for extraction of pharmaceutical compounds from biota samples and then analyzed using high-performance liquid chromatography. Of the 11 compounds, 10 were detected in biota species. Ibuprofen was the most frequently detected pharmaceutical in the biota tissues at high concentrations (<3.0-1225 ng/g, dw). The other widely detected compounds were fenoprofen (<3.6-323 ng/g, dw), gemfibrozil (<3.2-480 ng/g, dw), 17α-ethynylestradiol (<2.0-462 ng/g, dw), and carbamazepine (<7.6-222 ng/g, dw). The bioconcentration factors of the selected pharmaceuticals calculated in various aquatic organisms ranged from 9 to 2324 L/kg. The estimated daily intakes of anti-inflammatories, antiepileptics, lipid regulators, and hormones via seafood consumption were 0.37-568, 1.1-324, 8.5-197, 3-340 ng/kg bw. Day, respectively. Based on hazard quotients, estrone, 17ß-estradiol, and 17α-ethynylestradiol may pose a health risk to humans through the consumption of this seafood.

Determination and comparison of anionic surfactant and phosphate concentrations at the entrance and the exit of the Turkish Straits System (TSS).

A comparison study was performed on anionic surfactant and phosphate concentrations between the entrance and the exit of Turkish Straits System (TSS). Surface water samples were collected at fall season in 2016 and the spring season in 2017. According to the values obtained from the samples taken from 6 stations at the entrance and 7 at the exit, anionic surfactant values were high at the exit of the TSS, while the phosphate concentrations were relatively lower. The high phosphate values at the entrance are related to the eutrophic feature of the Black Sea. Also, the location of these stations covers one end of the Canal Istanbul Project, which is planned to be built soon, so the data of this study will constitute an important database.

Seasonal changes of LAS, phosphate, and chlorophyll-a concentrations in coastal surface water of the Prince Islands, Marmara Sea.

One-year monitoring study was performed on alkyl benzene sulphonate (LAS), phosphate, and chlorophyll-a concentrations in the Prince Islands between January and December of 2017. Surface water samples were collected monthly at one station at each island. The ranges of values of LAS, phosphate, and chlorophyll-a were found as 18.05-72.98 µg/L, 18.32-31.18 mg/L, and 0.31-6.35 µg/L, respectively, during all sampling periods throughout the islands. There were no significant differences in the concentrations of anionic detergent, phosphate, and chlorophyll-a within a year (p > 0.05), but a significant difference was observed between the stations (p < 0.05).

Comparison and origins of polycyclic aromatic hydrocarbons (PAHs) in the entrance and the exit of the Turkish Straits System (TSS).

Investigations of total petroleum hydrocarbons (TPHs) in water and polycyclic aromatic hydrocarbons (PAHs) in sediments were performed in the entrance and the exit of the Turkish Straits System (TSS) in autumn of 2016 and spring of 2017. TPH and PAH values ranged from 1.7 to 11.6 µg/l and 120 to 2912 ng/g (dw), respectively. On the basis of the given surface fluxes of the TSS, average petroleum flows were calculated as 1631 t/y from the Black Sea to the Marmara Sea and 8484 t/y from the Marmara Sea to the Aegean Sea. Pollution by PAHs ranged from relatively moderate to high. The most polluted sediments were collected from regions affected by shipping, such as Riva and Seddülbahir located at the entrance and the exit of the TSS, respectively. Moreover, origins of PAHs were determined using the ratios of PAH congeners. The main origins of PAHs were found as both pyrolytic and petrogenic at most stations.

Assessment of polycyclic aromatic hydrocarbons (PAHs) in mussels (Mytilus galloprovincialis) of Prince Islands, Marmara Sea.

In this study, PAH analyses have been conducted on indigenous mussels. Mussel samples (Mytilus galloprovincialis) have been collected from seven stations of Prince Islands during September 2015. Concentrations of total determined PAHs (sum of 16 compounds) ranged between 664 and 9083ngg(-1). The origin of PAHs has been found to be pyrolytic according to the PHE/ANT and FA/PYR ratios in Büyükada. For other islands, PAH origins have been observed as pyrolytic and petrogenic together according to the PHE/ANT, FA/PYR and BaA/CHR ratios.

T-PAH contamination in Mediterranean mussels (Mytilus galloprovincialis, Lamarck, 1819) at various stations of the Turkish Straits System.

Mussels (Mytilus galloprovincialis) from the Turkish Straits Systems were analyzed for sixteen parent polycyclic aromatic hydrocarbon (PAH) contents by high performance liquid chromatography (HPLC). This marine organism was selected because of its multitude, wide distribution, being bio indicator for the pollution and consumption by humans. Total PAH concentrations ranged from 1.2 to 589 µg g(-1) in Istanbul Strait, 0.94-36.4 µg g(-1) in Marmara Sea and 0.4-47.9 µg g(-1) in Çanakkale Strait during the samplings. According to the results Istanbul and Çanakkale Straits are more polluted than the Marmara Sea.