Synergetic Near- and Far-Field Plasmonic Effects for Optimal All-Perovskite Tandem Solar Cells with Maximized Infrared Absorption.

The efficiency and reliability of perovskite solar cells have rapidly increased in conjunction with the proposition of advanced single-junction and multi-junction designs that allow light harvesting to be maximized. However, Sn-based compositions required for optimized all-perovskite tandem devices have reduced absorption coefficients, as opposed to pure Pb perovskites. To overcome this, we investigate near- and far-field plasmonic effects to locally enhance the light absorption of infrared photons. Through optimization of the metal type, particle size, and volume concentration, we maximize effective light harvesting while minimizing parasitic absorption in all-perovskite tandem devices. Interestingly, incorporating 240 nm silver particles into the Pb-Sn perovskite layer with a volume concentration of 3.1% indicates an absolute power conversion efficiency enhancement of 2% in the tandem system. We present a promising avenue for experimentalists to realize ultrathin all-perovskite tandem devices with optimized charge carrier collection, diminishing the weight and the use of Pb.

Origin of anomalously stabilizing ice layers on methane gas hydrates near rock surface.

Gas hydrates (GHs) in water close to freezing temperatures can be stabilised via the formation of ice layers. In a recent work [Boström et al., Astron. Astrophys., A54, 650, 2021], it was found that a surface region with partial gas dilution could be essential for obtaining nano- to micron-sized anomalously stabilizing ice layers. In this paper, it is demonstrated that the Casimir-Lifshitz free energy in multi-layer systems could induce thinner, but more stable, ice layers in cavities than those found for gas hydrates in a large reservoir of cold water. The thickness and stability of such ice layers in a pore filled with cold water could influence the leakage of gas molecules. Additional contributions, e.g. from salt-induced stresses, can also be of importance, and are briefly discussed.

Silver Nanoparticle Chains for Ultra-Long-Range Plasmonic Waveguides for Nd3+ Fluorescence.

Plasmonic waveguides have been shown to be a promising approach to confine and transport electromagnetic energy beyond the diffraction limit. However, ohmic losses generally prevent their integration at micrometric or millimetric scales. Here, we present a gain-compensated plasmonic waveguide based on the integration of linear chains of Ag nanoparticles on an optically active Nd3+-doped solid-state gain medium. By means of dual confocal fluorescence microscopy, we demonstrate long-range optical energy propagation due to the near-field coupling between the plasmonic nanostructures and the Nd3+ ions. The subwavelength fluorescence guiding is monitored at distances of around 100 µm from the excitation source for two different emission ranges centered at around 900 nm and 1080 nm. In both cases, the guided fluorescence exhibits a strong polarization dependence, consistent with the polarization behavior of the plasmon resonance supported by the chain. The experimental results are interpreted through numerical simulations in quasi-infinite long chains, which corroborate the propagation features of the Ag nanoparticle chains at both excitation (λexc = 590 nm) and emission wavelengths. The obtained results exceed by an order of magnitude that of previous reports on electromagnetic energy transport using linear plasmonic chains. The work points out the potential of combining Ag nanoparticle chains with a small interparticle distance (~2 nm) with rare-earth-based optical gain media as ultra-long-range waveguides with extreme light confinement. The results offer new perspectives for the design of integrated hybrid plasmonic-photonic circuits based on rare-earth-activated solid-state platforms.

Effect of Spatial Inhomogeneity on Quantum Trapping.

An object that is immersed in a fluid and approaching a substrate may find a potential energy minimum at a certain distance due to the balance between attractive and repulsive Casimir-Lifshitz forces, a phenomenon referred to as quantum trapping. This equilibrium depends on the relative values of the dielectric functions of the materials involved. Herein, we study quantum trapping effects in planar nanocomposite materials and demonstrate that they are strongly dependent on the characteristics of the spatial inhomogeneity. As a model case, we consider spherical particles embedded in an otherwise homogeneous material. We propose an effective medium approximation that accounts for the effect of inclusions and find that an unprecedented and counterintuitive intense repulsive Casimir-Lifshitz force arises as a result of the strong optical scattering and absorption size-dependent resonances caused by their presence. Our results imply that the proper analysis of quantum trapping effects requires comprehensive knowledge and a detailed description of the potential inhomogeneity (caused by imperfections, pores, inclusions, and density variations) present in the materials involved.

Spatial coherence from Nd3+ quantum emitters mediated by a plasmonic chain.

Controlling the coherence properties of rare earth emitters in solid-state platforms in the absence of an optical cavity is highly desirable for quantum light-matter interfaces and photonic networks. Here, we demonstrate the possibility of generating directional and spatially coherent light from Nd3+ ions coupled to the longitudinal plasmonic mode of a chain of interacting Ag nanoparticles. The effect of the plasmonic chain on the Nd3+ emission is analyzed by Fourier microscopy. The results reveal the presence of an interference pattern in which the Nd3+ emission is enhanced at specific directions, as a distinctive signature of spatial coherence. Numerical simulations corroborate the need of near-field coherent coupling of the emitting ions with the plasmonic chain mode. The work provides fundamental insights for controlling the coherence properties of quantum emitters at room temperature and opens new avenues towards rare earth based nanoscale hybrid devices for quantum information or optical communication in nanocircuits.

Casimir-Lifshitz Force Based Optical Resonators.

We theoretically investigate the building of optical resonators based on the levitation properties of thin films subjected to strong repulsive Casimir-Lifshitz forces when immersed in an adequate medium and confronted with a planar substrate. We propose a design in which cavities supporting high Q-factor optical modes at visible frequencies can be achieved by means of combining commonly found materials, such as silicon oxide, polystyrene or gold, with glycerol as a mediating medium. We use the balance between flotation and repulsive Casimir-Lifshitz forces in the system to accurately tune the optical cavity thickness and hence its modes. The effects of other forces, such as electrostatic, that may come into play are also considered. Our results constitute a proof of concept that may open the route to the design of photonic architectures in environments in which dispersion forces play a substantial role and could be of particular relevance for devising novel microfluidic optical resonators.

Hybrid Plasmonic-Ferroelectric Architectures for Lasing and SHG Processes at the Nanoscale.

Coherent light sources providing sub-wavelength confined modes are in ever more demand to face new challenges in a variety of disciplines. Scalability and cost-effective production of these systems are also highly desired. The use of ferroelectrics in functional optical platforms, on which plasmonic arrangements can be formed, is revealed as a simple and powerful method to develop coherent light sources with improved and novel functionalities at the nanoscale. Two types of sources with sub-diffraction spatial confinement and improved performances are presented: i) plasmon-assisted solid-state nanolasers based on the interaction between metallic nanostructures and optically active rare earth doped ferroelectric crystals and ii) nonlinear radiation sources based on quadratic frequency mixing processes that are enhanced by means of localized surface plasmon (LSP) resonances. The mechanisms responsible for the intensification of the radiation-matter interaction processes by LSP resonances are discussed in each case. The challenges, potential applications, and future perspectives of the field are highlighted.

Absorption enhancement in methylammonium lead iodide perovskite solar cells with embedded arrays of dielectric particles.

In the field of hybrid organic-inorganic perovskite based photovoltaics, there is a growing interest in the exploration of novel and smarter ways to improve the cells light harvesting efficiency at targeted wavelength ranges within the minimum volume possible, as well as in the development of colored and/or semitransparent devices that could pave the way both to their architectonic integration and to their use in the flowering field of tandem solar cells. The work herein presented targets these different goals by means of the theoretical optimization of the optical design of standard opaque and semitransparent perovskite solar cells. In order to do so, we focus on the effect of harmless, compatible and commercially available dielectric inclusions within the absorbing material, methylammonium lead iodide (MAPI). Following a gradual and systematic process of analysis, we are capable of identifying the appearance of collective and hybrid (both localized and extended) photonic resonances which allow to significantly improve light harvesting and thus the overall efficiency of the standard device by above 10% with respect to the reference value while keeping the semiconductor film thickness to a minimum. We believe our results will be particularly relevant in the promising field of perovskite solar cell based tandem photovoltaic devices, which has posed new challenges to the solar energy community in order to maximize the performance of semitransparent cells, but also for applications focusing on architectonic integration.

Efficient bifacial dye-sensitized solar cells through disorder by design.

Herein we realize an optical design that optimizes the performance of bifacial solar cells without modifying any of the usually employed components. In order to do so, dielectric scatterers of controlled size and shape have been successfully integrated in the working electrodes of dye-sensitized solar cells (DSSCs), resulting in bifacial devices of outstanding performance. Power conversion efficiencies (PCEs) as high as 6.7% and 5.4% have been attained under front and rear illumination, respectively, which represent a 25% and a 33% PCE enhancement with respect to an 8 µm-thick standard solar cell electrode using platinum as the catalytic material. The remarkable bifacial character of our approach is demonstrated by the high rear/front efficiency ratio attained, around 80%, which is among the largest reported for this sort of device. The proposed optimized design is based on a Monte Carlo approach in which the multiple scattering of light within the cell is fully accounted for. We identified that the spherical shape of the scatterers is the key parameter controlling the angular distribution of the scattering, the most efficient devices being those in which the inclusions provide a narrow forward-oriented angular distribution of the scattered light.

High-Throughput Fabrication of Resonant Metamaterials with Ultrasmall Coaxial Apertures via Atomic Layer Lithography.

We combine atomic layer lithography and glancing-angle ion polishing to create wafer-scale metamaterials composed of dense arrays of ultrasmall coaxial nanocavities in gold films. This new fabrication scheme makes it possible to shrink the diameter and increase the packing density of 2 nm-gap coaxial resonators, an extreme subwavelength structure first manufactured via atomic layer lithography, both by a factor of 100 with respect to previous studies. We demonstrate that the nonpropagating zeroth-order Fabry-Pérot mode, which possesses slow light-like properties at the cutoff resonance, traps infrared light inside 2 nm gaps (gap volume ∼ λ(3)/10(6)). Notably, the annular gaps cover only 3% or less of the metal surface, while open-area normalized transmission is as high as 1700% at the epsilon-near-zero (ENZ) condition. The resulting energy accumulation alongside extraordinary optical transmission can benefit applications in nonlinear optics, optical trapping, and surface-enhanced spectroscopies. Furthermore, because the resonance wavelength is independent of the cavity length and dramatically red shifts as the gap size is reduced, large-area arrays can be constructed with λresonance ≫ period, making this fabrication method ideal for manufacturing resonant metamaterials.

Nanolevitation Phenomena in Real Plane-Parallel Systems Due to the Balance between Casimir and Gravity Forces.

We report on the theoretical analysis of equilibrium distances in real plane-parallel systems under the influence of Casimir and gravity forces at thermal equilibrium. Due to the balance between these forces, thin films of Teflon, silica, or polystyrene in a single-layer configuration and immersed in glycerol stand over a silicon substrate at certain stable or unstable positions depending on the material and the slab thickness. Hybrid systems containing silica and polystyrene, materials which display Casimir forces and equilibrium distances of opposite nature when considered individually, are analyzed in either bilayer arrangements or as composite systems made of a homogeneous matrix with small inclusions inside. For each configuration, equilibrium distances and their stability can be adjusted by fine-tuning of the volume occupied by each material. We find the specific conditions under which nanolevitation of realistic films should be observed. Our results indicate that thin films of real materials in plane-parallel configurations can be used to control suspension or stiction phenomena at the nanoscale.

An Optically Controlled Microscale Elevator Using Plasmonic Janus Particles.

In this article, we report how Janus particles, composed of a silica sphere with a gold half-shell, can be not only stably trapped by optical tweezers but also displaced controllably along the axis of the laser beam through a complex interplay between optical and thermal forces. Scattering forces orient the asymmetric particle, while strong absorption on the metal side induces a thermal gradient, resulting in particle motion. An increase in the laser power leads to an upward motion of the particle, while a decrease leads to a downward motion. We study this reversible axial displacement, including a hysteretic jump in the particle position that is a result of the complex pattern of a tightly focused laser beam structure above the focal plane. As a first application we simultaneously trap a spherical gold nanoparticle and show that we can control the distance between the two particles inside the trap. This photonic micron-scale "elevator" is a promising tool for thermal force studies, remote sensing, and optical and thermal micromanipulation experiments.

Optical trapping and manipulation of plasmonic nanoparticles: fundamentals, applications, and perspectives.

This feature article discusses the optical trapping and manipulation of plasmonic nanoparticles, an area of current interest with potential applications in nanofabrication, sensing, analytics, biology and medicine. We give an overview over the basic theoretical concepts relating to optical forces, plasmon resonances and plasmonic heating. We discuss fundamental studies of plasmonic particles in optical traps and the temperature profiles around them. We place a particular emphasis on our own work employing optically trapped plasmonic nanoparticles towards nanofabrication, manipulation of biomimetic objects and sensing.

Nanolithography by plasmonic heating and optical manipulation of gold nanoparticles.

Noble-metal particles feature intriguing optical properties, which can be utilized to manipulate them by means of light. Light absorbed by gold nanoparticles, for example, is very efficiently converted into heat, and single particles can thus be used as a fine tool to apply heat to a nanoscopic area. At the same time, gold nanoparticles are subject to optical forces when they are irradiated with a focused laser beam, which renders it possible to print, manipulate, and optically trap them in two and three dimensions. Here, we demonstrate how these properties can be used to control the polymerization reaction and thermal curing of polydimethylsiloxane (PDMS) at the nanoscale and how these findings can be applied to synthesize polymer nanostructures such as particles and nanowires with subdiffraction limited resolution.