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1.
Sci Total Environ ; 512-513: 622-630, 2015 Apr 15.
Article En | MEDLINE | ID: mdl-25655988

The purpose of this study is to assess personal exposures of skiers at the Alpine site of Plateau Rosà (45.9°N, 7.7°E, 3500 m a.s.l.), in the Valle d'Aosta region, Italy. The campaign was carried out on July 12th, 2011 during the summer ski season. A peak UVI value of 12.3, among the highest in Europe, was recorded on that day. Personal exposures (PE) were quantified using both polysulphone (PS) and poly-dimethyl phenylene oxide (PPO) dosimeters attached vertically to the cap because it is representative of the vertically oriented face of skiers. Exposure ratio (ER) defined as the ratio between PE and the corresponding ambient dose (i.e. erythemally weighted dose received by a horizontal surface) measured by a broad-band radiometer during the same exposure time of the subjects, was used to compare the results with previous studies. Skin color was also measured on the inner upper arm and on the cheek and differences in ITA (Individual Typology Angle) and a* (redness) values before and after exposure, were statistically analyzed. During the exposure period, the median PE (with PS) was 1.47 kJ m(-2) and that obtained by PPO was 1.15 kJ m(-2). The median of the ERs was 0.65 (min: 0.50, max: 0.83) considering the cumulative PS exposure and 0.46 (min: 0.29, max: 0.95) for PPO. An increase in ITAs on the exposed site (i.e. the skin became lighter) was observed after exposure. These results indicate that: a) for some skiers, the exposures were similar to those received on the horizontal plane; and b) the targeted population showed exposures above the occupational threshold limit value (TLV) defined by ICNIRP; c) the use of physical sunscreens which tend to leave a white cast, might have reduced skin color change. Nevertheless possible visible sun-induced skin-color changes could be observed after longer time intervals after exposure.


Environmental Exposure/statistics & numerical data , Radiation Dosage , Ultraviolet Rays , Female , Humans , Italy , Male , Sunlight
2.
Photochem Photobiol Sci ; 13(3): 521-30, 2014 Mar.
Article En | MEDLINE | ID: mdl-24352228

Polysulphone (PS) dosimetry is a well-known technique broadly used to assess the erythemally effective solar UV dose received by anatomical sites (personal exposure). We investigate the capability of PS dosimetry to convert doses absorbed by PS badges into biologically effective solar UV exposures taking as examples two relevant effects for human skin: erythema induction and pre-vitamin D3 production. PS calibration curves for erythemal and pre-vitamin D3 were distinctly determined by using an empirical relationship between the biologically effective UV exposures and the PS absorbance change. This relationship is parameterized by a coefficient, distinct for each of the two considered biological effects, multiplying the same cubic polynomial function. It is shown how the multiplying coefficient is related to the ratio between the biologically effective and the PS weighted irradiances which is the prevailing factor affecting the accuracy of the calibration and, consequently, the capability of PS films for measuring biologically effective solar UV exposures. The points addressed in this paper can be extended to other biological effects of interest whose action spectra have some similarity with the PS film response.


Film Dosimetry , Polymers/radiation effects , Skin/radiation effects , Sulfones/radiation effects , Sunlight , Ultraviolet Rays , Absorption , Algorithms , Calibration , Cholecalciferol/biosynthesis , Dose-Response Relationship, Radiation , Erythema/physiopathology , Humans , Linear Models , Models, Biological , Ozone , Polymers/chemistry , Skin/metabolism , Skin/physiopathology , Sulfones/chemistry
3.
Photochem Photobiol ; 88(1): 215-22, 2012.
Article En | MEDLINE | ID: mdl-22017203

Doses of erythemally weighted irradiances derived from polysulphone (PS) and electronic ultraviolet (EUV) dosimeters have been compared with measurements obtained using a reference spectroradiometer. PS dosimeters showed mean absolute deviations of 26% with a maximum deviation of 44%, the calibrated EUV dosimeters showed mean absolute deviations of 15% (maximum 33%) around noon during several test days in the northern hemisphere autumn. In the case of EUV dosimeters, measurements with various cut-off filters showed that part of the deviation from the CIE erythema action spectrum was due to a small, but significant sensitivity to visible radiation that varies between devices and which may be avoided by careful preselection. Usually the method of calibrating UV sensors by direct comparison to a reference instrument leads to reliable results. However, in some circumstances the quality of measurements made with simple sensors may be over-estimated. In the extreme case, a simple pyranometer can be used as a UV instrument, providing acceptable results for cloudless skies, but very poor results under cloudy conditions. It is concluded that while UV dosimeters are useful for their design purpose, namely to estimate personal UV exposures, they should not be regarded as an inexpensive replacement for meteorological grade instruments.


Radiation Dosage , Ultraviolet Rays , Calibration
4.
Photochem Photobiol ; 88(1): 207-14, 2012.
Article En | MEDLINE | ID: mdl-21978150

Polysulphone (PS) dosimetry has been a widely used technique for more than 30 years to quantify the erythemally effective UV dose received by anatomic sites (personal exposure). The calibration of PS dosimeters is an important issue as their spectral response is different from the erythemal action spectrum. It is performed exposing a set of PS dosimeters on a horizontal plane and measuring the UV doses received by dosimeters using calibrated spectroradiometers or radiometers. In this study, data collected during PS field campaigns (from 2004 to 2006), using horizontal and differently inclined dosimeters, were analyzed to provide some considerations on the transfer of the horizontal calibration to differently inclined dosimeters, as anatomic sites usually are. The role of sky conditions, of the angle of incidence between the sun and the normal to the slope, and of the type of surrounding surface on the calibration were investigated. It was concluded that PS horizontal calibrations apply to differently inclined dosimeters for incidence angles up to approximately 70° and for surfaces excluding ones with high albedo. Caution should be used in the application of horizontal calibrations for cases of high-incidence angle and/or high albedo surfaces.


Polymers/chemistry , Sulfones/chemistry , Calibration , Ultraviolet Rays
5.
Photochem Photobiol ; 87(4): 925-34, 2011.
Article En | MEDLINE | ID: mdl-21496028

A study to quantify the UV exposure of vineyard workers was carried out using polysulphone dosimetry. The study took place in Tuscany (Italy) involving 32 vineyard workers, covering three different stages of the vine's growth. The level of personal exposure expressed as a function on the available ambient UV radiation was determined. We also assessed skin reflectance parameters, pre and post exposure. It was found that during spring backs received between 53% and 87% of ambient exposure and arms between 30% and 60%. During summer, the workers received on the back between 36% and 77% of ambient exposure and between 19% and 43% of ambient exposure on the arm. The comparison with the occupational UV exposure limit showed that all subjects received UV exposures in excess of the limit. The exposure of back of neck exceeded 10 SED (assumed as a threshold level of sun-adapted skin for Mediterranean subjects) in spring, which means that in the case of non sun-adapted skin and without sun protection, erythema can be induced in this targeted population. The cumulative exposure was also estimated under specific assumptions of UV exposure giving values in some cases higher than previous studies.


Occupational Exposure/analysis , Radiation Dosage , Radiometry/methods , Skin/radiation effects , Adolescent , Adult , Agriculture , Erythema/prevention & control , Female , Humans , Italy , Male , Middle Aged , Models, Theoretical , Risk , Seasons , Solar System , Sunlight/adverse effects , Ultraviolet Rays/adverse effects , Wine
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