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In this perspective article, we discuss the application of ion implantation to manipulate strain (by either neutralizing or inducing compressive or tensile states) in suspended thin films. Emphasizing the pressing need for a high-mobility silicon-compatible transistor or a direct bandgap group-IV semiconductor that is compatible with complementary metal-oxide-semiconductor technology, we underscore the distinctive features of different methods of ion beam-induced alteration of material morphology. The article examines the precautions needed during experimental procedures and data analysis and explores routes for potential scalable adoption by the semiconductor industry. Finally, we briefly discuss how this highly controllable strain-inducing technique can facilitate enhanced manipulation of impurity-based spin quantum bits (qubits).
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Single impurities in insulators are now often used for quantum sensors and single photon sources, while nanoscale semiconductor doping features are being constructed for electrical contacts in quantum technology devices, implying that new methods for sensitive, non-destructive imaging of single- or few-atom structures are needed. X-ray fluorescence (XRF) can provide nanoscale imaging with chemical specificity, and features comprising as few as 100 000 atoms have been detected without any need for specialized or destructive sample preparation. Presently, the ultimate limits of sensitivity of XRF are unknown - here, gallium dopants in silicon are investigated using a high brilliance, synchrotron source collimated to a small spot. It is demonstrated that with a single-pixel integration time of 1 s, the sensitivity is sufficient to identify a single isolated feature of only 3000 Ga impurities (a mass of just 350 zg). With increased integration (25 s), 650 impurities can be detected. The results are quantified using a calibration sample consisting of precisely controlled numbers of implanted atoms in nanometer-sized structures. The results show that such features can now be mapped quantitatively when calibration samples are used, and suggest that, in the near future, planned upgrades to XRF facilities might achieve single-atom sensitivity.
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Typically used semiconducting metal oxides (SMOs) consist of several varying factors that affect gas sensor response, including film thickness, grain size, and notably the grain-grain junctions within the active device volume, which complicates the analysis and optimisation of sensor response. In comparison, devices containing a single nanostructured element do not present grain-grain junctions, and therefore present an excellent platform to comprehend the correlation between nanostructure surface stoichiometry and sensor response to the depletion layer (Debye length, LD) variation after the analyte gas adsorption/chemisorption. In this work, nanofabricated devices containing SnO2 and Sn3O4 individual nanobelts of different thicknesses were used to estimate their LD after NO2 exposure. In the presence of 40 ppm of NO2 at 150 °C, LD of 12 nm and 8 nm were obtained for SnO2 and Sn3O4, respectively. These values were associated to the sensor signals measured using multiple nanobelts onto interdigitated electrodes, outlining that the higher sensor signal of the Sn4+ surface (up to 708 for 100 ppm NO2 at 150°) in comparison with the Sn2+ (up to 185) can be explained based on a less depleted initial state and a lower surface electron affinity caused by the Lewis acid/base interactions with oxygen species from the baseline gas. To support the proposed mechanisms, we investigated the gas sensor response of SnO2 nanobelts with a higher quantity of oxygen vacancies and correlated the results to the SnO system.
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With the realization of larger and more complex space installations, an increase in the surface area exposed to atomic oxygen (AO) and ultraviolet (UV) effects is expected, making structural integrity of space structures essential for future development. In a low Earth orbit (LEO), the effects of AO and UV degradation can have devastating consequences for polymer and composite structures in satellites and space installations. Composite materials such as carbon fiber-reinforced polymer (CFRP) or polymer materials such as polyetherimide and polystyrene are widely used in satellite construction for various applications including structural components, thermal insulation, and importantly radio frequency (RF) assemblies. In this paper, we present a multilayered material protection solution, a multilayered protection barrier, that mitigates the effects of AO and UV without disrupting the functional performance of tested assemblies. This multilayered protection barrier deposited via a custom-built plasma-enhanced chemical vapor deposition (PECVD) system is designed so as to deposit all necessary layers without breaking vacuum to maximize the adhesion to the surface of the substrate and to ensure no pinhole erosion is present. In the multilayer solution, a moisture and outgassing barrier (MOB) is coupled with an AO and UV capping layer to provide complete protection.
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Metal-organic frameworks (MOFs) have emerged as an exciting class of porous materials that can be structurally designed by choosing particular components according to desired applications. Despite the wide interest in and many potential applications of MOFs, such as in gas storage, catalysis, sensing and drug delivery, electrical semiconductivity and its control is still rare. The use and fabrication of electronic devices with MOF-based components has not been widely explored, despite significant progress of these components made in recent years. Here we report the synthesis and properties of a new highly crystalline, electrochemically active, cobalt and naphthalene diimide-based MOF that is an efficient electrical semiconductor and has a broad absorption spectrum, from 300 to 2500 nm. Its semiconductivity was determined by direct voltage bias using a four-point device, and it features a wavelength dependant photoconductive-photoresistive dual behaviour, with a very high responsivity of 2.5 × 105 A W-1.
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We report on the fabrication and diffraction-limited characterization of parabolic focusing micromirrors. Sub-micron beam waists are measured for mirrors with 10-µm radius aperture and measured fixed focal lengths in the range from 24 µm to 36 µm. Optical characterization of the 3D intensity in the near-field produced when the device is illuminated with collimated light is performed using a modified confocal microscope. Results are compared directly with angular spectrum simulations, yielding strong agreement between experiment and theory, and identifying the competition between diffraction and focusing in the regime probed.
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The American Healthy Homes Survey, June 2005-March 2006, measured levels of lead and arsenic in homes nationwide. Based on a three-stage cluster sample of 1,131 housing units, key statistically weighted estimates of the prevalence of lead-based paint (LBP) and LBP hazards associated with paint, dust, and soil, and arsenic in dust and soil, were as follows: 37.1 million homes (35%) had some LBP; 23.2 million (22%) had one or more LBP hazards; 93% of the homes with LBP were built before 1978. The highest prevalence of LBP and LBP hazards was in the Northeast and Midwest. Over three million homes with children under six years of age had LBP hazards, including 1.1 million low-income households (< $30,000/yr.). Less than 5% of homes had detectable levels of arsenic in dust (≥ 5 µg/ft2). Arsenic in soil (for homes with yard soil) averaged 6.6 parts per million (ppm). Many homes had soil arsenic levels of 20 ppm or greater, including 16% of homes with wooden structures in the yard and 8% of homes without such structures.
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Arsénico/análisis , Exposición a Riesgos Ambientales , Contaminantes Ambientales/análisis , Vivienda , Plomo/análisis , Contaminantes Atmosféricos/análisis , Polvo/análisis , Monitoreo del Ambiente , Pintura/análisis , Contaminantes del Suelo/análisis , Estados UnidosRESUMEN
Mirrored carbon-spirals have been produced from pressured ferrocene via the bilateral extrusion of the spiral pairs from an iron core. A parametric plot of the surface geometry displays the fractal growth of the conical helix made with the logarithmic spiral. Electron microscopy studies show the core is a crystalline cementite which grows and transforms its shape from spherical to biconical as it extrudes two spiralling carbon arms. In a cross section along the arms we observe graphitic flakes arranged in a herringbone structure, normal to which defects propagate. Local-wave-pattern analysis reveals nanoscale defect patterns of two-fold symmetry around the core. The data suggest that the bilateral growth originates from a globular cementite crystal with molten surfaces and the nano-defects shape emerging hexagonal carbon into a fractal structure. Understanding and knowledge obtained provide a basis for the controlled production of advanced carbon materials with designed geometries.
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Compuestos Ferrosos/química , Grafito/química , Nanotubos de Carbono/química , Ensayo de Materiales , Metalocenos , Microscopía Electrónica de RastreoRESUMEN
Titania nanostructures are of increasing interest for a variety of applications, including photovoltaics, water splitting, and chemical sensing. Because of the photocatalytical properties of TiO2, chemical processes that occur at its surface can be exploited for highly efficient nanodevices. A facile and fast synthesis route has been explored that is free of catalysts or templates. An environmental scanning electron microscopy (ESEM) system was employed to grow titania nanowires (NWs) in a water vapor atmosphere (â¼1 mbar) and to monitor the growth in situ. In addition, the growth process was also demonstrated using a simple vacuum chamber. In both processes, a titanium filament was heated via the Joule effect and NWs were found to grow on its surface, as a result of thermal oxidation processes. A variety of nanostructures were observed across the filament, with morphologies changing with the wire temperature from the center to the end points. The longest NWs were obtained for temperatures between â¼730 °C and 810 °C. Typically, they have an approximate thickness of â¼300 nm and lengths of up to a few micrometers. Cross sections prepared by focused-ion-beam milling revealed the presence of a porous layer beneath the NW clusters. This indicates that the growth of NWs is driven by oxidation-induced stresses in the subsurface region of the Ti filament and by enhanced diffusion along grain boundaries. To demonstrate the potential of titania NWs grown via the hot filament method, single NW devices were fabricated and used for conductometric sensing of hydrogen sulfide (H2S) gas. The NW electric resistance was found to decrease in the presence of H2S. Its variation can be explained in terms of the surface depletion model.
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Self-organization of matter is essential for natural pattern formation, chemical synthesis, as well as modern material science. Here we show that isovolumetric reactions of a single organometallic precursor allow symmetry breaking events from iron nuclei to the creation of different symmetric carbon structures: microspheres, nanotubes, and mirrored spiraling microcones. A mathematical model, based on mass conservation and chemical composition, quantitatively explains the shape growth. The genesis of such could have significant implications for material design.
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The U.S. Department of Housing and Urban Development in collaboration with the United States Environmental Protection Agency conducted a survey measuring lead, allergens, and insecticides in a randomly selected nationally representative sample of residential homes. Multistage sampling with clustering was used to select the 1131 homes of which a subset of 500 randomly selected homes included the collection of hard surface floor wipes. Samples were collected by trained field technicians between June 2005 and March 2006 using isopropanol wetted wipes. Samples were analyzed for a suite of 24 compounds which included insecticides in the organochlorine, organophosphate, pyrethroid and phenylpyrazole classes, and the insecticide synergist piperonyl butoxide. The most commonly detected were permethrin (89%), chlorpyrifos (78%), chlordane (64%), piperonyl butoxide (52%), cypermethrin (46%), and fipronil (40%). Mean and geometric mean (GM) concentrations varied widely among compounds, but were highest for trans-permethrin (mean 2.22 ng/cm2 and GM 0.14 ng/ cm2) and cypermethrin (mean 2.9 ng/cm2 and GM 0.03 ng/ cm2). Results show that most floors in occupied homes in the U.S. have measurable levels of insecticides that may serve as sources of exposure to occupants.
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Contaminación del Aire Interior , Pisos y Cubiertas de Piso , Vivienda , Plaguicidas/química , Recolección de Datos , Monitoreo del Ambiente , Control de CalidadRESUMEN
We propose an experimental technique that allows us a straightforward and reliable fabrication of magnetic and electromechanical nanodevices for single particle detection and characterization. We demonstrate three different experimental methods for fabrication of nanoscale devices consisting of either single or multiwall carbon nanotubes bridging metallic electrodes and decorated with magnetic iron/iron oxide nanocubes with a size of 18 nm. Electrical characterization of the devices as well as structural and magnetic investigations of nanoparticles are reported. In particular, the proposed method based on measurements of the magnetic resonance in a single nanoparticle will enable dynamic magnetic resonance measurements on a single magnetic nanoparticle with a moment of approximately 10(5) mu(B) that are not feasible using conventional experimental techniques.
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Electrical measurements of freestanding multiwall carbon nanotubes using high resistance tunnelling contacts reveal a power law behaviour, I alpha V alpha + 1, with alpha as high as 5.2, followed by a transition to an offset ohmic behaviour. The freestanding electrode geometry allows for a distinction between the predictions from Luttinger liquid and environmental quantum fluctuation (EQF) theories to be made. The high values of exponents found are explained within the EQF formulism, where reflections resulting from the impedance discontinuity caused by the freestanding geometry are included.
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We present for the first time an in-depth study of the RF response of a single-walled carbon nanotube (SWCNT) rope. Our novel electrode design, based on a tapered coplanar approach, allows for single tube measurements well into the GHz regime, minimizing substrate-related parasitics. From the analysis of the S-parameters, the ac transport mechanism in the range 30 kHz to 6 GHz is established. This work is an essential prerequisite for the fabrication of high-speed devices based on bundles of nanowires or low-dimensional structures.