Coupling effect of reaction conditions on the catalytic activity of Cu-Mn composite oxide catalysts for toluene.

Volatile organic compounds (VOCs) are one of the major components of air pollution. Catalytic combustion is a promising technology for the treatment of VOCs and at its center is the preparation of efficient and cheap catalysts. In this study, by loading copper (Cu) and manganese (Mn) on Santa Barbara Amorphous-15 (SBA-15) molecular sieve, the Cux-Mny/SBA-15 (x = 1, 2; y = 1, 2) composite metal oxide catalyst was prepared using the equal volume impregnation method. Their performance in the toluene catalytic combustion reaction was investigated by adjusting the molar ratio (x : y), and the loading of Cu and Mn. The results of the Brunner-Emmett-Teller (BET), X-ray diffraction (XRD), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS) analyses show that the CuMnO spinel phase can be detected in the Cu-Mn composite metal oxide catalyst doped with a low concentration of Cu. The overall rod-like structure of the fibrous network structure provides a large specific surface area, and the particle crystallinity is low and the dispersion is good. Due to the synergistic effect of Cu and Mn, the greater the amount of Mn3+ and adsorbed oxygen species (Oads) that are available, and the higher the turnover frequency (TOF) value, the better and more superior catalytic performance and excellent stability is obtained, when compared with the single-component oxides used in toluene catalytic combustion. After a continuous catalytic reaction for 12 h, the toluene conversion rate remained above 95%. The coupling effect of the catalytic reaction temperature and concentration of oxygen on the catalytic combustion of toluene was also studied. At a low reaction temperature (<250 °C), the increase of the concentration of oxygen played a superior role in promoting the conversion of toluene. The kinetic analysis of the toluene catalytic combustion process showed that the catalytic combustion of toluene by Cu-Mn/SBA-15 followed both the Mars-Van Krevelen (MVK) and Langmuir-Hinshelwood (L-H) reaction mechanisms. With the increase of the Oads amount caused by the decrease of the Cu ratio, the proportion of the L-H reaction mechanism increases.

Meeting the heavy-metal safety requirements for food crops by using biochar: An investigation using sunflower as a representative plant under different atmospheric CO2 concentrations.

Global warming impacts on plant growth and food safety are emerging topics of concern, while biochar as a soil additive benefits plants. This study investigates (1) sunflower plant growth at various biochar concentrations in a soil-compost growing substrate under both ambient (420 ppm) and elevated (740 ppm) atmospheric CO2 concentrations, and (2) concentrations of heavy metals in the growing substrates and organs of the plants. The elevated CO2 concentration benefits the vegetative parts but harms the reproductive parts of the plants. Additionally, the elevated CO2 concentration inhibits the beneficial effects that biochar confers on the plants at the ambient concentration. The optimum biochar concentration at both CO2 levels was found to be 15%. At the time of harvest, most of the heavy-metal concentrations in the growing substrate increased. It was demonstrated that biochar can reduce the amount of heavy metals that accumulate in the roots and seeds whose heavy-metal concentrations complied with Singapore food safety regulations, while those for the biochar met the proposed Singapore biochar standard's thresholds. Our results show that the proposed Singapore biochar standard is practical and sound.

Machine learning and circular bioeconomy: Building new resource efficiency from diverse waste streams.

Biorefinery systems are playing pivotal roles in the technological support of resource efficiency for circular bioeconomy. Meanwhile, artificial intelligence presents great potential in handling scientific tasks of high-dimensional complexity. This review article scrutinizes the status of machine learning (ML) applications in four critical biorefinery systems (i.e. composting, fermentation, anaerobic digestion, and thermochemical conversions) as well as their advancements against traditional modeling techniques of mechanistic approach. The contents cover their algorithm selections, modeling challenges, and prospective improvements. Perspectives are sketched to further inform collective efforts on crucial aspects. The multidisciplinary interchange of modeling knowledge will enable a more progressive digital transformation of sustainability efforts in supporting sustainable development goals.

Advancing the bioconversion process of food waste into methane: A systematic review.

With the continuous rise of food waste (FW) throughout the world, a research effort to reveal its potential for bioenergy production is surging. There is a lack of harmonized information and publications available that evaluate the state-of-advance for FW-derived methane production process, particularly from an engineering and sustainability point of view. Anaerobic digestion (AD) has shown remarkable efficiency in the bioconversion of FW to methane. This paper reviews the current research progress, gaps, and prospects in pre-AD, AD, and post-AD processes of FW-derived methane production. Briefly, the review highlights innovative FW collection and optimization routes such as AI that enable efficient FW valorization processes. As weather changes and the FW sources may affect the AD efficiency, it is important to assess the spatio-seasonal variations and microphysical properties of the FW to be valorized. In that case, developing weather-resistant bioreactors and cost-effective mechanisms to modify the raw substrate morphology is necessary. An AI-guided reactor could have high performance when the internal environment of the centralized operation is monitored in real-time and not susceptible to changes in FW variety. Monitoring solvent degradation and fugitive gases during biogas purification is a challenging task, especially for large-scale plants. Furthermore, this review links scientific evidence in the field with full-scale case studies from different countries. It also highlights the potential contribution of ADFW to carbon neutrality efforts. Regarding future research needs, in addition to the smart collection scheme, attention should be paid to the management and utilization of FW impurities, to ensure sustainable AD operations.

A Review on Enhancing Cupriavidus necator Fermentation for Poly(3-hydroxybutyrate) (PHB) Production From Low-Cost Carbon Sources.

In the context of a circular economy, bioplastic production using biodegradable materials such as poly(3-hydroxybutyrate) (PHB) has been proposed as a promising solution to fundamentally solve the disposal issue of plastic waste. PHB production techniques through fermentation of PHB-accumulating microbes such as Cupriavidus necator have been revolutionized over the past several years with the development of new strategies such as metabolic engineering. This review comprehensively summarizes the latest PHB production technologies via Cupriavidus necator fermentation. The mechanism of the biosynthesis pathway for PHB production was first assessed. PHB production efficiencies of common carbon sources, including food waste, lignocellulosic materials, glycerol, and carbon dioxide, were then summarized and critically analyzed. The key findings in enhancing strategies for PHB production in recent years, including pre-treatment methods, nutrient limitations, feeding optimization strategies, and metabolism engineering strategies, were summarized. Furthermore, technical challenges and future prospects of strategies for enhanced production efficiencies of PHB were also highlighted. Based on the overview of the current enhancing technologies, more pilot-scale and larger-scale tests are essential for future implementation of enhancing strategies in full-scale biogas plants. Critical analyses of various enhancing strategies would facilitate the establishment of more sustainable microbial fermentation systems for better waste management and greater efficiency of PHB production.

High-Efficiency, Mass-Producible, and Colored Solar Photovoltaics Enabled by Self-Assembled Photonic Glass.

Building-integrated photovoltaics is a crucial technology for developing zero-energy buildings and sustainable cities, while great efforts are required to make photovoltaic (PV) panels aesthetically pleasing. This places an urgent demand on PV colorization technology that has a low impact on power conversion efficiency (PCE) and is simultaneously mass-producible at a low cost. To address this challenge, this study contributes a colorization strategy for solar PVs based on short-range correlated dielectric microspheres, i.e., photonic glass. Through theoretical studies, first we demonstrate that the photonic glass self-assembled by high-index microspheres could enable both colored solar cells and modules, with easily variable colors and negligible parasitic absorption. By a fast spray coating process of colloidal monodisperse ZnS microspheres, we show the photonic glass layer could be easily deposited on silicon solar cells, enabling them to have structural colors. Through varying microsphere sizes, solar cells with different colors are achieved, showing low PCE loss compared to normal black cells. These colored solar cells are also encapsulated with a general lamination process to produce PV modules with various colors and patterns at a stunning PCE approaching 21%. Moreover, the long-term stability is subsequently verified by aging tests including an outdoor exposure for 10 days and a damp-heat test for 1000 h, and the mass producibility is demonstrated by presenting a colored PV panel with an output power over 108 W. These results confirm photonic glass as a promising strategy for colored PVs possessing high efficiency and practical applicability.

Microbial succession analysis reveals the significance of restoring functional microorganisms during rescue of failed anaerobic digesters by bioaugmentation of nano-biochar-amended digestate.

Nano-biochar application was investigated for anaerobic digestion of orange peel waste. The application for methane production focused on the optimization of biochar feedstock, rescue of failed digesters, and microbial succession analysis. It showed that sewage sludge (SS) derived biochar had the highest performance enhancement among the different feedstocks, which could be ascribed to the improvement of electron transfer, interspecies hydrogen transfer, and supply of trace elements. Subsequently, nano SS biochar-amended digestate was evaluated for rescuing failed digesters, and the experimental results indicated its positive roles through gradual bioaugmentation operation. The dynamic analysis of microbial succession indicated the successful application was through the mechanism of restoring partially the functional microbial communities. The major reconstruction of functional microorganisms included bacteria phyla Hydrogenispora (24.5%) and Defluviitoga (18.8%) as well as methanogenic genera of Methanosarcina (41.5%) and Methanobacterium (27.3%). These findings would contribute to rescuing failed anaerobic digesters by bioaugmentation with biochar-amended digestate.

Methodological framework for wastewater treatment plants delivering expanded service: Economic tradeoffs and technological decisions.

With emerging decarbonization to deploy more integrated waste management, there is a burgeoning need for re-managing waste-related infrastructures in urban environments. Wastewater treatment plants are key contributors to expanded environmental services, but relevant technological decisions and economic tradeoffs have to be assessed from a systems perspective. This study provides a methodological framework that consolidates the multiple technological and economic aspects of system retrofitting for such an evaluation purpose. Complex leachate from refuse transfer stations has been recently identified as the decarbonization roadblock of urban waste management, and it was chosen for investigations by this new methodological approach. The system impacts by complex leachate on the existing facilities were validated by experimental trials. To derive the financial outlooks for decision making, the evaluation matrix includes the quantitative impacts of bioenergy profiles, energy balance analysis of biogas utilization methods, needs of system retrofitting, economic factors, and their uncertainties. Due to the detected inefficiency of bioenergy recovery, bioinformatic analysis was proceeded for understanding the underlying mechanism to propose a mitigation solution. Overall, the methodological framework can provide a quantitative assessment of the centralized capability of wastewater treatment plants for systems planning in the new policy agenda of urban decarbonization, where the methodological potentials of expanded framework applications are also highlighted.

Plastic-containing food waste conversion to biomethane, syngas, and biochar via anaerobic digestion and gasification: Focusing on reactor performance, microbial community analysis, and energy balance assessment.

To manage the mixture of food waste and plastic waste, a hybrid biological and thermal system was investigated for converting plastic-containing food waste (PCFW) into renewable energy, focusing on performance evaluation, microbial community analysis, and energy balance assessment. The results showed that anaerobic digestion (AD) of food waste, polyethylene (PE)-containing food waste, polystyrene (PS)-containing food waste, and polypropylene (PP)-containing food waste generated a methane yield of 520.8, 395.6, 504.2, and 479.8 mL CH4/gVS, respectively. CO2 gasification of all the plastic-containing digestate produced more syngas than pure digestate gasification. Syngas from PS-digestate reached the maximum yield of 20.78 mol/kg. During the digestate-derived-biochar-amended AD of PCFW, the methane yields in the biochars-amended digesters were 6-30% higher than those of the control digesters. Bioinformatic analysis of microbial communities confirmed the significant difference between control and biochar-amended digesters in terms of bacterial and methanogenic compositions. The enhanced methane yields in biochars-amended digesters could be partially ascribed to the selective enrichment of genus Methanosarcina, leading to an improved equilibrium between hydrogenotrophic and acetoclastic methanogenesis pathways. Moreover, energy balance assessment demonstrated that the hybrid biological and thermal conversion system can be a promising technical option for the treatment of PCFW and recovery of renewable biofuels (i.e., biogas and syngas) and bioresource (i.e., biochar) on an industrial scale.

Viability of a practical multicyclic sorption-based water harvester with improved water yield.

Sorption-based atmospheric water harvesting (SAWH) has emerged as an attractive way to relieve water scarcity. However, the daily water yield of currently reported SAWH devices remains low to satisfy the rising demand for drinking water. The sorption and desorption kinetics, long-term stability and especially facile scaling-fabrication of adsorbents and scaled-up device implementation have become the bottleneck to such large-scale SAWH application. To overcome these challenges, an air-cooled SAWH device was fabricated to investigate its atmospheric water harvesting (AWH) performance under real island climate and its feasibility of multicyclic operation. Under monocyclic operation, the device demonstrated the superior water productivity as much as 3.9 kg day-1, or 0.39 kgwater kgadsorbent-1 day-1, at 31 °C and 70% RH, with a thermal efficiency of 25.4% (desorption at 94 °C). The SAWH device demonstrated successful water production through 2 adsorption-desorption cycles within one day, with increased thermal efficiency to as high as 32.2% and increased water harvesting performance up to 0.42 kgwater kgadsorbent-1 day-1 by 20-90%. This is the first demonstration in multicyclic SAWH at large scales, holding the promise of large-scale and practical water supply in island areas while opening up new applications such as indoor dehumidification.

Research on Combustion Properties and Pollutant Emission Characteristics of Blends of Maltol Byproduct/Pine Sawdust.

In this paper, the combustion and pollutant emission characteristics of maltol byproduct, pine sawdust, and their blends were experimentally studied by thermogravimetry, tube furnace experiment, and scanning electron microscopy. The results show that the combustion process of maltol byproduct, pine sawdust, and their blends can be divided into three stages, in which the volatile release of the maltol byproduct includes two stages. The ignition temperature of the blended fuel is lower than that of sawdust. The NO x produced by combustion of the blended fuel is lower than that produced by sawdust combustion alone, and the SO2 emission is always at a low level. There is a certain synergy between maltol byproduct and pine sawdust mixed combustion. Comprehensively comparing the combustion characteristics and emission characteristics, the blended fuel made by adding less than 10% maltol byproduct into pine sawdust can improve the combustion characteristics and reduce emissions, and 10% is the best proportion of the blended fuel.

Enhancing microbial lipids yield for biodiesel production by oleaginous yeast Lipomyces starkeyi fermentation: A review.

The enhanced production of microbial lipids suitable for manufacturing biodiesel from oleaginous yeast Lipomyces starkeyi is critically reviewed. Recent advances in several aspects involving the biosynthetic pathways of lipids, current conversion efficiencies using various carbon sources, intensification strategies for improving lipid yield and productivity in L. starkeyi fermentation, and lipid extraction approaches are analyzed from about 100 papers for the past decade. Key findings on strategies are summarized, including (1) optimization of parameters, (2) cascading two-stage systems, (3) metabolic engineering strategies, (4) mutagenesis followed by selection, and (5) co-cultivation of yeast and algae. The current technical limitations are analyzed. Research suggestions like examination of more gene targets via metabolic engineering are proposed. This is the first comprehensive review on the latest technical advances in strategies from the perspective of process and metabolic engineering to further increase the lipid yield and productivity from L. starkeyi fermentation.

Two-Stage Fermentation of Lipomyces starkeyi for Production of Microbial Lipids and Biodiesel.

The high operating cost is currently a limitation to industrialize microbial lipids production by the yeast Lipomyces starkeyi. To explore economic fermentation technology, the two-stage fermentation of Lipomyces starkeyi using yeast extract peptone dextrose (YPD) medium, orange peel (OP) hydrolysate medium, and their mixed medium were investigated for seven days by monitoring OD600 values, pH values, cell growth status, C/N ratios, total carbon concentration, total nitrogen concentration, residual sugar concentration, lipid content, lipid titer, and fatty acids profiles of lipids. The results showed that two-stage fermentation with YPD and 50% YPD + 50% OP medium contributed to lipid accumulation, leading to larger internal lipid droplets in the yeast cells. However, the cells in pure OP hydrolysate grew abnormally, showing skinny and angular shapes. Compared to the one-stage fermentation, the two-stage fermentation enhanced lipid contents by 18.5%, 27.1%, and 21.4% in the flasks with YPD medium, OP medium, and 50%YPD + 50%OP medium, and enhanced the lipid titer by 77.8%, 13.6%, and 63.0%, respectively. The microbial lipids obtained from both one-stage and two-stage fermentation showed no significant difference in fatty acid compositions, which were mainly dominated by palmitic acid (33.36-38.43%) and oleic acid (46.6-48.12%). Hence, a mixture of commercial medium and lignocellulosic biomass hydrolysate could be a promising option to balance the operating cost and lipid production.

Quantifying techno-economic indicators' impact on isolated renewable energy systems.

Addressing climate change with the rising global energy usage necessitates electricity sector decarbonization by rapidly moving toward flexible and efficient off-grid renewable energy systems (RESs). This paper analyzes the wind and solar micro-grids, with batteries and pumped hydro storage for a robust off-grid RES techno-economic operation, while considering diverse multi-objective optimization cases. This research has considered the RES variable operational losses in the developed methodology and relations between different indicators are evaluated, revealing a basic understanding between them. The results reveal that the reliability index is inversely related to the oversupply index, while directly related to the system self-sufficiency index. The cost of energy is more sensitive to technical indicators rather than the storage cost and so can be used as a primary monetary index. Energy and cost balance analysis showed that 16%-20% of the used energy was drained in RES operational losses, which were usually ignored in previous studies.

Effects of plastics on reactor performance and microbial communities during acidogenic fermentation of food waste for production of volatile fatty acids.

The aim of this work was to study the effects of plastics (high-density polyethylene (HDPE), polystyrene (PS), polypropylene (PP), and polyethylene terephthalate (PET)) on reactor performance and microbial communities during acidogenic fermentation of food waste for the production of volatile fatty acids (VFA). The addition of HDPE and PS increased total VFA yields by 28% and 47%, respectively, whereas the addition of PP and PET decreased total VFA yields by 6% and 2%, respectively. The highest enhancing performance of PS could be ascribed to its highly porous structure that could provide immobilization effects for microbial growth. Degradation of various plastics was confirmed by FESEM results, but the degrees were limited (i.e., 3.9-8.7%). Bacterial analysis showed that the addition of various plastics altered the community diversity. Phylum Thermotogae and genus Defluviitoga dominated all the reactors. Potential HDPE- and PS-degrading microbes could belong to genus Clostridium_sensu_stricto_8, while Tepidanaerobacter_syntrophicus could be PET-degrading microbes.

System integration of hydrothermal liquefaction and anaerobic digestion for wet biomass valorization: Biodegradability and microbial syntrophy.

Sewage sludge treatment & disposal pose environmental challenges in populated-dense urban environments. Due to its poor digestibility and dewaterability, sewage sludge contains high water content and concentrated nutrients (carbon, nitrogen, and phosphorus) even after conditioning and mechanical thickening. Regarding this, a pretreatment step and downstream anaerobic digestion (AD) are often required. To meet our societal goal towards a circular economy, system integration of hydrothermal pretreatment and AD now present an attractive approach for recovering resources from the wet sewage sludge biomass. In this study, such system integration together with struvite precipitation was applied for valorizing sewage sludge. Firstly, hydrothermal conditions of different temperatures (160 °C-230 °C) and duration (2 h-12 h) were compared to their performance of nutrients solubilization. Subsequently, the hydrothermal condition of 220°C-3 h was selected for further investigations of struvite recovery and bioenergy production. Through AD comparisons, the integrated process improved the ultimate biomethane yield by 38%. Interestingly, a lag phase occurred in the midst of the AD, which indicated the need for microbial acclimatization after the hydrothermal process. The long-term microbial monitoring revealed the efficient biomethane re-generation was closely related to the late enrichment of Syntrophus for potential H2-syntrophy. Therefore, on one hand, this study investigated an efficient and integrated approach of sewage sludge valorization. On other hand, it uncovered the microbial bottlenecks and potential biotechnological means for further system improvement. Further research about nutrients speciation in the integrated system would be desired.

Three-dimensional non-isothermal numerical model for predicting semi-volatile organic compound transport process in a room.

In this paper, a three-dimensional non-isothermal computational model for predicting indoor SVOC distribution is proposed, considering the effects of turbulence diffusion and suspended particles. The realizable k-ε model is introduced for turbulent flow simulation in a room. The Euler-Euler method is adopted to deal with the gas-particle two-phase flow coupled problem. Inertia slip velocity and irreversible first-order absorption boundary are employed for more accurate prediction of particle motion. The simulated curve of outlet gas-phase di-2-ethylhexyl phthalate (DEHP) concentration with emission time is verified by available experimental data. The emission process of DEHP in a 15 m2 room in Beijing during 100 days with or without air cleaner is simulated by the developed model considering air leak through window and door gaps. It is found that if the air cleaner keeps on all the time during 100 days the gas-phase DEHP concentration in the room will tend to be uniform, while the emission process is far from equilibrium without an air cleaner even the emission lasts 100 days. Results also suggest that floor heating, decrease of particle concentration, weaken of heat transfer, enhancement of mass transfer, and air infiltration in window gap contribute to decrease DEHP concentration.

Mixing effects on decentralized high-solid digester for horticultural waste: Startup, operation and sensitive microorganisms.

This work studied the use of a horizontal high-solid digester for the decentralized anaerobic treatment of horticultural waste (fallen leaves), where the effect of intermittent mixing by a modified double helical ribbon impeller was investigated. Before experimental verification, the flow pattern and theoretical mixing time were first characterized by CFD simulation. Subsequently, three mixing time intervals (i.e., 3 min/3 hr; 18 min/3 hr; 108 min/3 hr) and one control setup (i.e., without mixing) were compared for their performance during start-up and semi-continuous operation. It was found that minimal mixing was necessary for an efficient digester's start-up but increased mixing intensity for semi-continuous operation. The results were further interpreted by correlating the digester performance and microbial communities. Those microorganisms sensitive to increased mixing intensity were highlighted and analysed.

Gasification biochar from horticultural waste: An exemplar of the circular economy in Singapore.

Organic waste, the predominant component of global solid waste, has never been higher, resulting in increased landfilling, incineration, and open dumping that releases greenhouse gases and toxins that contribute to global warming and environmental pollution. The need to create and adopt sustainable closed-loop systems for waste reduction and valorization is critical. Using organic waste as a feedstock, gasification and pyrolysis systems can produce biooil, syngas, and thermal energy, while reducing waste mass by as much as 85-95% through conversion into biochar, a valuable byproduct with myriad uses from soil conditioning to bioremediation and carbon sequestration. Here, we present a novel case study detailing the circular economy of gasification biochar in Singapore's Gardens by the Bay. Biochar produced from horticultural waste within the Gardens was tested as a partial peat moss substitute in growing lettuce, pak choi, and pansy, and found to be a viable substitute for peat moss. At low percentages of 20-30% gasification biochar, fresh weight yields for lettuce and pak choi were comparable to or exceeded those of plants grown in pure peat moss. The biochar was also analyzed as a potential additive to concrete, with a 2% biochar mortar compound found to be of suitable strength for non-structural functions, such as sidewalks, ditches, and other civil applications. These results demonstrate the global potential of circular economies based on local biochar creation and on-site use through the valorization of horticultural waste via gasification, generating clean, renewable heat or electricity, and producing a carbon-neutral to -negative byproduct in the form of biochar. They also indicate the potential of scaled-up pyrolysis or gasification systems for a circular economy in waste management.

Biochar utilisation in the anaerobic digestion of food waste for the creation of a circular economy via biogas upgrading and digestate treatment.

A wood waste-derived biochar was applied to food-waste anaerobic digestion to evaluate the feasibility of its utilisation to create a circular economy. This biochar was first purposed for the upgrading of the biogas from the said anaerobic digestion, before treating and recovering the nutrients in the solid fraction of the digestate, which was finally employed as a biofertilizer for the organic cultivation of three green leafy vegetables: kale, lettuce and rocket salad. Whilst the amount of CO2 the biochar could absorb from the biogas was low (11.17 mg g-1), it could potentially be increased by modifying through physical and chemical methods. Virgin as well as CO2-laden biochar were able to remove around 31% of chemical oxygen demand, 8% of the ammonia and almost 90% of the total suspended solids from the digestate wastewater, which was better than a dewatering process via centrifugation but worse than the industry standard of a polytetrafluoroethylene membrane bioreactor. Nutrients were recovered in the solid fraction of the digestate residue filtered by the biochar, and utilised as a biofertilizer that performed similarly to a commercial complete fertilizer in terms of aerial fresh weight growth for all three vegetables cultivated. Contingent on the optimal upgrading of biogas, the concept of a circular economy based on biochar and anaerobic digestion appears to be feasible.