Monitoring of rainwater quality in Kandy and Peradeniya, Sri Lanka.

The composition of atmospheric deposition is a measure of air quality, an important aspect of the health of the ecosystem. Consequently, continuous monitoring of atmospheric deposition is crucial to obtain remedial measures to avoid undesirable aspects that would affect living things. In this context, the objective of this study was to determine the rainwater quality at selected locations in Kandy and Peradeniya area of Sri Lanka, namely, Kandy, Polgolla, and University of Peradeniya (UOP), and to identify possible correlations between quality parameters through statistical means. Forty (40) rainwater samples from the UOP site and seven (07) samples each from the Kandy and Polgolla sites were collected from 18 May 2020 to 28 April 2021. The volume-weighted average (VWA) pH values of UOP, Kandy, and Polgolla sites were determined to be 7.44, 7.19, and 7.19, respectively, and moreover, acid rain (pH < 5.6) occurrences were not detected during the sampling period. The VWA values of rainfall, conductivity, salinity, TDS, and hardness at the UOP site were 40.12 mm, 51.93 µS cm-1, 0.0300 ppt, 26.59 mg L-1, and 13.55 mg L-1, respectively. The corresponding values of the Kandy site were 16.52 mm, 64.04 µS cm-1, 0.0361 ppt, 30.80 mg L-1, and 19.49 mg L-1, respectively; and those of the Polgolla site were 33.10 mm, 53.90 µS cm-1, 0.0310 ppt, 25.76 mg L-1, and 19.31 mg L-1, respectively. The VWA values of conductivity, salinity, and TDS were the highest at the Kandy site. Further, the VWA values of hardness at Kandy and Polgolla sites were approximately equal, probably due to the spring of Ca2+ and Mg2+ particulates from the dolomite quarry located in Digana area. The most prominent anion was identified as Cl- in bulk deposition at all three sites, while NO3- showed the lowest concentration of all sites. Moreover, very strong significant positive correlations were identified between conductivity-TDS, conductivity-salinity, conductivity-hardness, TDS-hardness, TDS-salinity, salinity-hardness, SO42--Cl-, and NO3--Cl- according to the relevant Pearson correlation coefficients. It is thus concluded that the pollutants come from the same sources, either natural or anthropogenic.

Staphylococcus edaphicus KCB02A11 incorporated with natural adsorbents: first report on its tolerance and removal of hexavalent chromium [Cr(VI)].

Deteriorating the quality of different parts of the ecosystem due to toxic metals is a serious global issue. Hexavalent chromium is a metal that can cause adverse effects on all living beings, including plants, animals, and microorganisms, on exposure to high concentrations for prolonged periods. Removing hexavalent chromium from various types of wastes is challenging; hence the present study investigated the use of bacteria incorporated with selected natural substrates in removing hexavalent chromium from water. Isolated Staphylococcus edaphicus KCB02A11 has shown higher removal efficiency with a wide hexavalent chromium range (0.025-8.5 mg/L) within 96 h. Incorporating the isolated strain with natural substrates commonly found in the environment (hay and wood husk) showed high removal potential [100% removal with 8.5 mg/L of Cr(VI)], even within less than 72 h, with the formation of biofilms on the used substrates applied for metal removal on a large scale for prolonged periods. This study is the first report investigating hexavalent chromium tolerance and removal by Staphylococcus edaphicus KCB02A11.

Potential use of Chlorella vulgaris KCBAL01 from a freshwater stream receiving treated textile effluent in hexavalent chromium [Cr(VI)] removal in extremely acidic conditions.

Remediation of hexavalent chromium with conventional chemical and physical methods is a costly process, while replacing some critical steps in physiochemical remediation with self-sustaining bioremediation agents are expected to be cost-effective and environmentally friendly implementation. In this study, a microalga isolated from a freshwater stream receiving treated textile wastewater was identified up to its molecular level and investigated its ability to tolerate and remove hexavalent chromium from extremely acidic conditions under different temperatures. The ability of microalgae to tolerate and remove Cr(VI) was investigated by growing it in BG11 media with different pH (1, 2, 3 & 7), amended with several concentrations of Cr(VI) and incubated under different temperatures for 96 hrs. Microalga was identified as Chlorella vulgaris and found that the isolated strain has a higher hexavalent chromium removal potential in extremely acidic conditions than in neutral pH conditions at 25 °C. In contrast, its Cr(VI) removal potential is significantly influenced by the pH and temperature of the growth medium. Furthermore, it exhibited a permanent viability loss at extreme acidic conditions (pH 1 - 3) and prolonged exposure to the higher chromium content. The microalga investigated will be a highly useful bioagent in hexavalent chromium remediation in high acidic conditions.

Chemical characteristics of wet precipitation at Peradeniya in Sri Lanka.

The purpose of this research was to study chemical characteristics of precipitation in Peradeniya (Latitude 6.973701, Longitude 79.915256), Kandy District in Sri Lanka. This study was conducted during 2012 to 2014, and wet precipitation was analyzed for pH, conductivity, Na+, NH4+, K+, Mg2+, Ca2+, F-, Cl-, NO3-, SO42-, Pb, Cu, Mn, Al, Zn, and Fe for a total of 125 samples. Less than 2% events of acidic precipitation were recorded, and the VWA of the major ionic species present in precipitation samples were in the order of Ca2+ > Na+ > Cl- > NH4+ > SO42- > K+ > NO3- > Mg2+. Neutralization of acidity of precipitation is much more related to CaCO3 than NH3, and the presence of high content of Ca2+ strongly supports this fact. When considering marine contribution, SO42-/Na+, Ca2+/Na+, Mg2+/Na+, and K+/Na+ ratios are higher than the reference value suggesting that contribution of sources other than marine. Concentration of Zn is the highest while that of Mn is the lowest. Principal component analysis identified probable sources for major ionic and elemental sources as both natural and anthropogenic sources such as vehicular emission due to heavy traffic, waste incineration, bio mass burning, brass industry, and construction.

Atmospheric chemical composition of bulk deposition at two geographically distinct locations in Sri Lanka.

This study presented the research work carried out for the investigation of chemical composition of bulk precipitation in two geographically and economically distinct areas, namely Gampaha and Kandy Districts. This study was conducted from 2013 to 2014 at three sampling stations in each District. The bulk precipitation was analyzed for pH, conductivity, Na+, NH4+, K+, Mg2+, Ca2+, F-, Cl-, NO3-, SO42-, Pb, Cu, Mn, Al, Zn and Fe for a total of 375 samples. Only 8% events of acidic precipitation were recorded in Gampaha District when compared with 3% in Kandy District. The volume weighted average concentrations of the major ionic species present in precipitation samples were in the order of Na+ > Ca2+ > Cl- > NH4+ > SO42- > Mg2+ > NO3- > K+ > F- in the Gampaha stations, while the order was NH4+ > Ca2+ > Na+ > Cl- > SO42- > Mg2+ > NO3- > K+ > F- in Kandy District. Neutralization of acidity of precipitation is much more related to CaCO3 than NH3, and high content of Ca2+ ions present in both Districts strongly supports this fact. When considering marine contribution, SO42-/Na+, Ca2+/Na+ and Mg2+/Na+ ratios are higher than the reference value suggesting contribution of sources other than marine. Depositions of both Districts show that the concentration of Al is the highest while that of Mn is the lowest. Principal component analysis suggests that influencing human activities on chemical composition of rain water depends on thermal power plant, oil refinery, heavy traffic and waste incineration in the study area.