RESUMEN
The agglomeration and low conductivity of molybdenum disulfide (MoS2) electrocatalysts restrict the presentation of its real intrinsic reaction activity, which leads to challenges for the high-performance hydrogen evolution reaction (HER). Herein, a well-dispersed and superhydrophilic/superaerophobic MoS2 catalyst with uniform three-dimensional conductive networks have been prepared assisted with cellulose nanofiber (CNF) and carboxylated multi-walled carbon nanotubes (cMWCNT). The resulted CNF/cMWCNT/MoS2 catalysts present a superhydrophilic/superaerophobic state with contact angles for water and bubble of 0° and 154.1° respectively. This structure effectively disperses MoS2 nanoparticles through uniform embeddedness and promotes gas-liquid mass transfer via wettability. Benefiting from these optimizations, the CNF/cMWCNT/MoS2 exhibits better HER performance and a low overpotential (154 mV @ 10 mA/cm2). Encourangingly, CNF/cMWCNT/MoS2 catalysts have a slight decay of 6.99 % at 10 mA/cm2 after 100 h, while the cMWCNT/MoS2 shows a decay of 35.83 %. This approach using natural CNF for well-dispersed catalysts provides a potential for high-performance HER electrode design.