RESUMEN
Biomass combustion releases a complex array of Volatile Organic Compounds (VOCs) that pose significant challenges to air quality and human health. Although biomass burning has been extensively studied at ecosystem levels, understanding the atmospheric transformation and impact on air quality of emissions in urban environments remains challenging due to complex sources and burning materials. In this study, we investigate the VOC emission rates and atmospheric chemical processing of predominantly wood burning emissions in a small urban centre in Greece. Ioannina is situated in a valley within the Dinaric Alps and experiences intense atmospheric pollution accumulation during winter due to its topography and high wood burning activity. During pollution event days, the ambient mixing ratios of key VOC species were found to be similar to those reported for major urban centres worldwide. Positive matrix factorisation (PMF) analysis revealed that biomass burning was the dominant emission source (>50 %), representing two thirds of OH reactivity, which indicates a highly reactive atmospheric mixture. Calculated OH reactivity ranges from 5 s-1 to an unprecedented 278 s-1, and averages at 93 ± 66 s-1 at 9 PM, indicating the presence of exceptionally reactive VOCs. The highly pronounced photochemical formation of organic acids coincided with the formation of ozone, highlighting the significance of secondary formation of pollutants in poorly ventilated urban areas. Our findings underscore the pressing need to transition from wood burning to environmentally friendly sources of energy in poorly ventilated urban areas, in order to improve air quality and safeguard public health.
RESUMEN
Reconciling top-down and bottom-up country-level greenhouse gas emission estimates remains a key challenge in the MRV (Monitoring, Reporting, Verification) paradigm. Here we propose to independently quantify cumulative emissions from a significant number of methane (CH4) emitters at national level and derive robust constraints for the national inventory. Methane emissions in Cyprus, an insular country, stem primarily from waste and agricultural activities. We performed 24 intensive survey days of mobile measurements of CH4 from October 2020 to September 2021 at emission 'hotspots' in Cyprus accounting together for about 28 % of national CH4 emissions. The surveyed areas include a large active landfill (Koshi, 8 % of total emissions), a large closed landfill (Kotsiatis, 18 %), and a concentrated cattle farm area (Aradippou, 2 %). Emission rates for each site were estimated using repeated downwind transects and a Gaussian plume dispersion model. The calculated methane emissions from landfills of Koshi and Kotsiatis (25.9 ± 6.4 Gg yr-1) and enteric fermentation of cattle (10.4 ± 4.4 Gg yr-1) were about 129 % and 40 % larger, respectively than the bottom-up sectorial annual estimates used in the national UNFCCC inventory. The parametrization of the Gaussian plume model dominates the uncertainty in our method, with a typical 21 % uncertainty. Seasonal variations have little influence on the results. We show that using an ensemble of in situ measurements targeting representative methane emission hotspots with consistent temporal and spatial coverage can contribute to the monitoring and validation of national bottom-up emission inventories.
RESUMEN
The emission factors (EFs) for a broad range of semivolatile organic chemicals (SVOCs) from subtropical eucalypt forest and tropical savannah fires were determined for the first time from in situ investigations. Significantly higher (t test, P < 0.01) EFs (µg kg-1 dry fuel, gas + particle-associated) for polycyclic aromatic hydrocarbons (∑13 PAHs) were determined from the subtropical forest fire (7,000 ± 170) compared to the tropical savannah fires (1,600 ± 110), due to the approximately 60-fold higher EFs for 3-ring PAHs from the former. EF data for many PAHs from the eucalypt forest fire were comparable with those previously reported from pine and fir forest combustion events. EFs for other SVOCs including polychlorinated biphenyl (PCB), polychlorinated naphthalene (PCN), and polybrominated diphenyl ether (PBDE) congeners as well as some pesticides (e.g., permethrin) were determined from the subtropical eucalypt forest fire. The highest concentrations of total suspended particles, PAHs, PCBs, PCNs, and PBDEs, were typically observed in the flaming phase of combustion. However, concentrations of levoglucosan and some pesticides such as permethrin peaked during the smoldering phase. Along a transect (10-150-350 m) from the forest fire, concentration decrease for PCBs during flaming was faster compared to PAHs, while levoglucosan concentrations increased.
