Transfer of trace organic compounds in an operational soil-aquifer treatment system assessed through an intrinsic tracer test and transport modelling.

Soil Aquifer Treatment (SAT) can provide supplementary treatment of trace organic compounds (TrOCs) such as pharmaceutical and industrial compounds present in Secondary Treated Wastewater (STWW). Concern on presence of unregulated TrOCs in natural systems has raised recently as well as the interest in SAT systems for remediation. The present study quantifies, at the field scale over35 m of lateral groundwater flow, the effectiveness of the Agon-Coutainville SAT system (Manche, Normandy, France) for TrOCs removal by sorption and biodegradation through monitoring of seven TrOCs (oxazepam, carbamazepine, benzotriazole, tolyltriazole, caffein, paracetamol, ibuprofen) and major inorganic compounds as intrinsic tracers in STWW and groundwater during a 34-day STWW infiltration experiment during operational use of the SAT. Cationic exchanges and mixing between groundwater and STWW during the experiment were highlighted by major ions and geochemical simulations. Due to the low thickness of the unsaturated zone, a 1D analytical solution of the advection-dispersion equation (ADE) was applied on chloride data. Chloride was used as conservative intrinsic tracer to calibrate the horizontal flow and transport parameters such as the aquifer dispersion coefficient (D) and the average pore water velocity (ν) allowing estimation of the groundwater residence time. Transport and attenuation of the TrOCs were simulated assuming first-order degradation constant (µ) and linear retardation coefficient (R), calibrated to simulate the observed temporal changes in the breakthrough of TrOCs. Sorption was found to play a role in the transport of TrOCs, notably for oxazepam with a higher linear retardation coefficient value of 2.2, whereas no significant differences of retardation were observed for carbamazepine, tolyltriazole, benzotriazole (1.37, 1.35, 1.36 respectively). Estimated first order degradation rate constants, between 0.03d-1 for carbamazepine and 0.09d-1 for tolyltriazole, were generally high compared to the literature, possibly due to favourable redox conditions and important microbial activities within the system. This study provides evidence of the efficiency of the Agon-Coutainville SAT system for the removal of TrOCs.

Sampling waste printed circuit boards: Achieving the right combination between particle size and sample mass to measure metal content.

The current worldwide expansion of waste PCB (WPCB) deposits represents both a pressing environmental issue and an economic opportunity, fostering the development of numerous recycling processes across the world. An important input for designing such processes is the metallic content of WPCBs, which is assayed by grinding and leaching samples taken from the stack of WPCBs to be recycled. The content values come with substantial uncertainties, arising mainly from the uneven distribution of the metals within the structure of WPCBs. This study aims to quantify the effects on these uncertainties of the particle size, the mass of the sample digested and the number of digestion replicates. It focused on the abundance of six metals in WPCBs: Cu, Fe, Zn, Pb and Ni, and also Co, which is a critical element for the EU. A batch of 485 kg of WPCBs was put through several shredding and splitting steps to produce three fractions: one shredded to 2 mm, and two ground to 750 µm and 200 µm. From each sample, 16 samples of 0.5 g, 2 g or 5 g were digested in hot aqua regia. Bootstrapping of the results allowed the error around the mean content to be estimated, for each metal and for all the experimental conditions. Considering the largest sample masses and three replicated digestions, the uncertainties for Zn (resp. Ni) were reduced from 35% to 10% (resp. from 70% to 10%) when the particle size was reduced from 2 mm to 200 µm.