1.
Spectrochim Acta A Mol Biomol Spectrosc
; 60(6): 1299-305, 2004 May.
Artículo
en Inglés
| MEDLINE
| ID: mdl-15134727
RESUMEN
The composition of the co-ordination sphere of Cu(II) dithiocarbamate mixed-ligand complexes Cu(Et2)dtc)X (X = Cl-, Br-) and Cu(Et2)dtc)(+)...Y- (Y- = ClO4-, NO3-) is studied from the combined analysis of spectrophotometric and EPR data. The results obtained about CT-photolysis of the complexes in EtOH and i-PrOH are compared with our previous data of photolysis in chloromethane/ROH solutions. Reaction mechanism and the role of alcohol are discussed on the ground of electronic and EPR spectra and quantum yield results.